46780-31-8

Basic information

• Product Name: (S)-2-methylpentyl tosylate
• CAS NO: 46780-31-8
• Molecular Weight: 256.366
• Mol File: 46780-31-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (S)-2-methylpentyl tosylate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-methylpentyl tosylate(46780-31-8)
• EPA Substance Registry System: (S)-2-methylpentyl tosylate(46780-31-8)

Safety Data

• Hazardous Substances Data: 46780-31-8(Hazardous Substances Data)

Upstream product

• 49642-47-9 methyl (R)-2-methylbutyric acid 
• 161905-09-5 (S)-2-methyl-1-(tetrahydropyranyloxy)pentane 
• 105-30-6 (S)-2-methyl-1-pentanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 105-30-6 (R)-2-methylpentan-1-ol 
• 161794-90-7 (R)-2-methyl-1-(tetrahydropyranyloxy)pentane 

Downstream Products

• 13364-16-4 (S)-2-Methylpentylamin 
• 161795-01-3 (3S,7S)-3,7-dimethyldecyl tosylate 
• 161795-02-4 (3R,7S)-3,7-dimethyldecyl tosylate 
• 161794-94-1 (3S,7S)-1-(benzyloxy)-3,7-dimethyldecane 
• 161794-95-2 (3R,7S)-1-(benzyloxy)-3,7-dimethyldecane 
• 161795-03-5 (3S,7R)-3,7-dimethyldecyl tosylate 
• 161795-00-2 (3R,7R)-3,7-dimethyldecyl tosylate 
• 162938-42-3 (3S,7R)-1-(benzyloxy)-3,7-dimethyldecane 
• 161794-93-0 (3R,7R)-1-(benzyloxy)-3,7-dimethyldecane 
• 120748-62-1 Toluene-4-sulfonic acid (S)-4-methyl-heptyl ester 
• 115109-00-7 (R)-1-tosyloxy-4-methylheptane 
• 149065-61-2 (R)-1-bromo-2-methylpentane 

Relevant articles and documents

Metathesis-mediated synthesis of (R)-10-Methyl-2-tridecanone, the southern corn rootworm pheromone

(R)-10-Methyl-2-tridecanone, the female sex pheromone of the southern corn rootworm (Diabrotica undecimpunctata howardi Barber), was synthesized in 9 steps from methyl (S)-3-hydroxy-2-methylpropanoate in a 15.7% overall yield. Olefin cross metathesis between (R)-6-methyl-1-nonene and 5-hexen-2-one employing Grubbs' first-generation catalyst was the key step of the synthesis.

Pheromone Synthesis, CLXVII. - Synthesis of All of the Eight Stereoisomers of Methyl 2,6,10-Trimethyltridecanoate, the Male-produced Pheromone of the Stink Bugs, Euschistus heros and E. obscurus

All of the eight possible stereoisomers of methyl 2,6,10-trimethyltridecanoate (1), the male-produced attractant pheromone of the South American soybean pest, Euschistus heros, and that of E. obscurus, are synthesized by starting from the enantiomers of citronellol (2) and methyl 3-hydroxy-2-methylpropanoate (9). - Key Words: Euschistus heros / Euschistus obscurus / Pheromones / Stink bugs / Sulfones, alkylation of / Tridecanoate, methyl 2,6,10-trimethyl-