47107-74-4

Basic information

• Product Name: iodo(triphenylphosphino)copper
• Synonyms: iodo(triphenylphosphino)copper;Iod(triphenylphosphino)kupfer;iodo(triphenylphosphine)-coppe;iodo(triphenylphosphine)-Copper;Copper, iodo(triphenylphosphine)-
• CAS NO: 47107-74-4
• Molecular Formula: C₁₈H₁₅CuIP
• Molecular Weight: 517.707273
• EINECS: 256-296-9
• Product Categories: Organometallics
• Mol File: 47107-74-4.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 360°Cat760mmHg
• Flash Point: 181.7°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 4.74E-05mmHg at 25°C
• Water Solubility: 730μg/L at 20.9℃
• CAS DataBase Reference: iodo(triphenylphosphino)copper(CAS DataBase Reference)
• NIST Chemistry Reference: iodo(triphenylphosphino)copper(47107-74-4)
• EPA Substance Registry System: iodo(triphenylphosphino)copper(47107-74-4)

Safety Data

• Hazardous Substances Data: 47107-74-4(Hazardous Substances Data)

Usage

Flammability and Explosibility

Notclassified

InChI:InChI=1/C18H15P.Cu.HI/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1

Upstream product

• 7681-65-4 copper(l) iodide 
• 603-35-0 triphenylphosphine 
• 136983-12-5 trans-Pt(I)(C₆H₄F-p)(PEt₃)2 
• 190141-85-6 trans-Pt(I)(C₆H₄OMe-p)(PEt₃)2 
• 190141-84-5 trans-Pd(I)(C₆H₄Me-p)(PEt₃)2 
• 1435-01-4 N-phenyl-2-(thiophen-2-ylmethylene)-hydrazinecarbothioamide 
• 110682-61-6 bis(η-cyclopentadienyl)(μ-carbonyl)(μ-bis(diphenylphosphino)methane)(μ-copperchloride)dirhodium 

Downstream Products

• 166529-17-5 Cu(P(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=[Cu(P(C₆H₅)3)2]PF₆ 
• 1071788-52-7 Cu(PPh₃)((EtO)2P(O)CH₂C₆H₄-4-[NHC(S)NP(S)(O-i-Pr)2]) 
• 113352-38-8 {(C₆H₅)4P}{Cu(bis(trifluoromethyl)ethylenediselenolato)2} 
• 55172-29-7 thallium chloride 
• 429-06-1 N,N,N,N-tetraethylammonium tetrafluoroborate 

Relevant articles and documents

Crystal structure of copper(I) thiosemicarbazone complex [CuI(PPh3)(catsc)]

In this paper, we report the preparation of a four-coordinated copper(I) thiosemicarbazone complex [CuI(PPh3)(catsc)] from the reaction of PPh3 and catsc (3-phenylpropenalthiosemicarbazone) with CuI. The synthesized complex is characterized by elemental analyses (CHNS) and FT-IR spectroscopy. The crystal structure of [CuI(PPh3)(catsc)] is investigated by single crystal X-ray diffraction. The catsc coordinates to the copper(I) ion as a bidentate ligand via the N and S atoms. The complex has a distorted tetrahedral coordination geometry.

Steric demands in the formation of heteroleptic Cu(I) complexes with α-diimines and triphenylphosphine

The synthesis and the study of the molecular structure of a series of heteroleptic copper(I) compounds with triphenylphosphine and α-diimines presenting a varying degree of bulk at their chelating cite is reported. The most sterically crowded diimine acts as a monodentate ligand towards copper(I) promoting bridging of the halogen atom present in the metal coordination sphere and formation of a dimer. Evidence for this behavior is obtained from the electronic spectra and semiempirical quantum chemical calculations with MOPAC. Steric demands in all the studied compounds preclude coordination of silver(I) under similar reaction conditions.

Copper(I)-catalyzed stereoselective synthesis of (1E,3E)-2- sulfonyl-1,3-dienes from N-propargylic sulfonohydrazones

A new method for the stereoselective synthesis of highly substituted (1E,3E)-2-sulfonyl-1,3-dienes from N-propargylic sulfonohydrazone derivatives has been developed via copper(I)-catalyzed [3,3] rearrangement and highly regioselective migration of the sulfonyl group. Copyright