4713-59-1

Basic information

• Product Name: Diphenyldibromostannane
• Synonyms: Dibromodiphenylstannane;Diphenyldibromostannane
• CAS NO: 4713-59-1
• Molecular Formula: C₁₂H₁₀Br₂Sn
• Molecular Weight: 432.73
• Mol File: 4713-59-1.mol
• Article Data: 11

Chemical Properties

• Melting Point: 38°C
• Boiling Point: 358.3°Cat760mmHg
• Flash Point: 170.5°C
• Appearance: /solid
• Density: g/cm³
• Vapor Pressure: 5.29E-05mmHg at 25°C
• CAS DataBase Reference: Diphenyldibromostannane(CAS DataBase Reference)
• NIST Chemistry Reference: Diphenyldibromostannane(4713-59-1)
• EPA Substance Registry System: Diphenyldibromostannane(4713-59-1)

Safety Data

• Hazardous Substances Data: 4713-59-1(Hazardous Substances Data)

Usage

InChI:InChI=1/2C6H5.2BrH.Sn/c2*1-2-4-6-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2/rC12H10Br2Sn/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

Upstream product

• 639-58-7 triphenyltin chloride 
• 7726-95-6 bromine 
• 5054-50-2 Diphenyl-bis-(phenylethinyl)-zinn 
• 161838-12-6 (C₆H₅)3SnCH₂CHCHC₆H₅ 
• 10294-33-4 boron tribromide 
• 60080-20-8 tin(IV) bis(acetylacetonate) dichloride 
• 100-58-3 phenylmagnesium bromide 
• 81134-68-1 di-[1]naphthyl-diphenyl stannane 
• 7789-33-5 iodine(I) bromide 
• 81134-67-0 [1]naphthyl-triphenyl stannane 
• 1135-99-5 diphenyltin(IV) dichloride 
• 595-90-4 tetraphenyltin(IV) 
• 7789-67-5 stannic bromide 
• 13450-92-5 germanium tetrabromide 

Downstream Products

• 20298-26-4 Br(C₆H₅)2SnCo(CO)4 
• 10203-52-8 diethyl(diphenyl)tin 
• 105860-16-0 (C₆H₅)2Sn(P(C₆H₅)2)2 
• 36869-27-9 (C₆H₅)2Sn{Co(CO)4}2 
• 125883-97-8 (C₆H₅)2Sn(P(C₆H₁₁)2)2 
• 142764-80-5 (C₆H₅)2SnBr(SSP(OC₂H₅)2) 
• 98077-10-2 (C₆H₅)2SnBr(SSC(OC₂H₅)) 

Relevant articles and documents

Thiazole complexes of diorganotinf(IV) dihalides: The crystal structure of dichlorodiphenylbis(thiazole) tint(IV)

The reaction of thiazole (Tz) with diorganotin(IV) dihalides yielded compounds of type [SnR2X2(Tz)2] (R = Me, Et, Ph; X - Cl, Br). The structure of dichlorodiphenylbis(thiazole)tin(IV) was determined by X-ray diffraction. The crystals are monoclinic (space group P21/c) and consist of discrete trans-SnPh2Cl2(Tz)2 units with the metal atom coordinated to two Cl atoms, two phenyl carbons, and the N atoms of two thiazole rings. Moessbauer and IR spectra suggest similar trans-stereochemistry for the other complexes prepared. The behavior of these compounds in solution was studied by conductimetry and NMR techniques.

New bis-o-benzosemiquinonato tin(IV) complexes

New bis-o-benzosemiquinonato tin(IV) complexes (3,6-SQ) 2SnCl2, (3,6-SQ)2SnBr2 and (3,6-SQ)2SnPh2 (3,6-SQ is radical-anion 3,6-di-tert-butyl-o-benzosemiquinone) were synthesized by differen

A novel route for the preparation of dimeric tetraorganodistannoxanes

The reaction of polymeric diorganotin oxides, (R2SnO)n (R = Me, Et, n-Bu, n-Oct, c-Hex, i -Pr, Ph), with saturated aqueous NH4X (X = F, Cl, Br, I, OAc) in refluxing 1,4-dioxane afforded in high yields dimeric tetraorganodistannoxanes, [R2(X)SnOSn(X)R2]2, and in a few cases diorganotin dihalides or diacetates, R2SnX2. The reported method appears suitable for the synthesis of fluorinated tetraorganodistannoxanes. Identification of [R2(OH)SnOSn(X)R2]2 (R=n-Bu; X = Cl, Br) and [R2(OH)SnOSn(X)R2] [R2(X)SnOSn(X)R2] suggest a serial substitution mechanism starting from [R2(OH)SnOSn(OH)R2]2. X-ray crystal structure determinations are reported for [Me2(AcO)SnOSn(OAc)Me2]2 (29a), [i-Pr2(Br)SnOSn(Br)i-Pr2]2 (20a), [c-Hex2 (F)SnOSn(F)c-Hex2]2 (5a) and [c-Hex2(F)SnOSn(Cl)c-Hex2]2 (36), respectively. These show the presence of a central (R2Sn)2O2 core that is connected, via the oxygen atoms, to R2Sn entities. Acetate (29a) or halides (5a, 20a, 36) complete the coordination about the tin centres.