474712-27-1

Basic information

• Product Name: μ-oxo-bis[(bromo)tri-m-tolylantimony]
• CAS NO: 474712-27-1
• Molecular Weight: 966.103
• Mol File: 474712-27-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: μ-oxo-bis[(bromo)tri-m-tolylantimony](CAS DataBase Reference)
• NIST Chemistry Reference: μ-oxo-bis[(bromo)tri-m-tolylantimony](474712-27-1)
• EPA Substance Registry System: μ-oxo-bis[(bromo)tri-m-tolylantimony](474712-27-1)

Safety Data

• Hazardous Substances Data: 474712-27-1(Hazardous Substances Data)

Upstream product

• 10035-10-6 hydrogen bromide 
• 7722-84-1 dihydrogen peroxide 
• 35569-54-1 Tri-m-tolyl-stibane 

Relevant articles and documents

μ-Oxo-bis[(bromo)tri-m-tolylantimony]: Synthesis and structure

μ-Oxo-bis[(bromo)tri-m-tolylantimony] was synthesized by the reaction of tri-m-tolylstibine with hydrobromic acid in ether in the presence of hydrogen peroxide. The complex was structurally characterized by X-ray diffraction analysis. The coordination polyhedron of the Sb atoms is a distorted trigonal bipyramid with the bromine and the bridging O atoms in the axial positions. The Sb(1)-C(Ph) distances vary from 2.085(9) to 2.111(8) A. The Sb(1)-Br(1) and Sb(2)-Br(2) bond lengths are 2.739(2) and 2.735(2) A, respectively; the Sb-Obr distances measure 1.949(1) A.