477952-40-2Relevant articles and documents
Enantioselective alkene radical cations reactions
Crich, David,Shirai, Michio,Brebion, Franck,Rumthao, Sochanchingwung
, p. 6501 - 6518 (2007/10/03)
The reaction of enantiomerically enriched 2-methyl-2-nitro-3-(diphenylphosphatoxy)alkyl radicals with tributyltin hydride and AIBN in benzene at reflux results in the formation of alkene radical cation/anion pairs, which are trapped intramolecularly by am
Enantioselective cyclization of alkene radical cations
Crich, David,Shirai, Michio,Rumthao, Sochanchingwung
, p. 3767 - 3769 (2007/10/03)
(Matrix Presented) Enantiomerically enriched β-(diphenylphosphatoxy) nitroalkanes undergo radical ionic fragmentation, induced by tributyltin hydride and AIBN in benzene at reflux, to give alkene radical cations in contact radical ion pairs. These contact