47864-81-3

Basic information

• Product Name: Ir(η-cyclo-octa-1,5-diene)(triphenylphosphine)2(1+)
• CAS NO: 47864-81-3
• Molecular Weight: 824.985
• Mol File: 47864-81-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Ir(η-cyclo-octa-1,5-diene)(triphenylphosphine)2(1+)(CAS DataBase Reference)
• NIST Chemistry Reference: Ir(η-cyclo-octa-1,5-diene)(triphenylphosphine)2(1+)(47864-81-3)
• EPA Substance Registry System: Ir(η-cyclo-octa-1,5-diene)(triphenylphosphine)2(1+)(47864-81-3)

Safety Data

• Hazardous Substances Data: 47864-81-3(Hazardous Substances Data)

Upstream product

• 12115-50-3 IrCl(η-cyclo-octa-1,5-diene)(triphenylphosphine) 
• 603-32-7 triphenyl-arsane 
• 2923-28-6 silver trifluoromethanesulfonate 
• 65804-43-5 cis,trans,cis-[Ir(H)2(PPh₃)2(Me₂CO)2]PF₆ 
• 5259-72-3 cyclo-octa-1,5-diene 

Downstream Products

• 12115-50-3 IrCl(η-cyclo-octa-1,5-diene)(triphenylphosphine) 

Relevant articles and documents

Anomalous reactivity of triphenylarsine and triarylphosphines of low basicity with [Ir(cod)(py) 2][PF6] and use of the complexes as precatalysts for imine hydrogenation

Reaction of [Ir(cod)(py)2][PF6] with PPh3 or P(C6H4-4-F)3 gives the bis(phosphine) derivative [Ir(cod)L2][PF6], but with the poorly basic phosphine P(C6Hsu