478943-98-5

Basic information

• Product Name: Ethanone, 1-[(1R,4R,5S)-5-hydroxybicyclo[2.2.1]hept-2-yl]-, rel- (9CI)
• Synonyms: Ethanone, 1-[(1R,4R,5S)-5-hydroxybicyclo[2.2.1]hept-2-yl]-, rel- (9CI)
• CAS NO: 478943-98-5
• Molecular Formula: C9H14O2
• Molecular Weight: 154.20626
• Product Categories: CYCLOPENTANE;ACETYLGROUP
• Mol File: 478943-98-5.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-[(1R,4R,5S)-5-hydroxybicyclo[2.2.1]hept-2-yl]-, rel- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[(1R,4R,5S)-5-hydroxybicyclo[2.2.1]hept-2-yl]-, rel- (9CI)(478943-98-5)
• EPA Substance Registry System: Ethanone, 1-[(1R,4R,5S)-5-hydroxybicyclo[2.2.1]hept-2-yl]-, rel- (9CI)(478943-98-5)

Safety Data

• Hazardous Substances Data: 478943-98-5(Hazardous Substances Data)

Upstream product

• 824-60-2 exo-5-acetyl-2-norbornene 
• 5063-03-6 2-acetyl-5-norbornene 

Relevant articles and documents

Selective hydroboration of alkenes and alkynes in the presence of aldehydes and ketones

The reactions of terminal alkenes in the presence of ketones or aldehydes with a variety of borane reagents have been investigated. It was found that the selective hydroboration of a terminal alkene in the presence of a ketone or an aldehyde is most efficient when dicyclohexylborane is used as the hydroborating agent. The hydroboration of olefinic ketones and olefinic aldehydes with dicyclohexylborane generates the corresponding hydroxyaldehydes and hydroxyketones in good yields after oxidation with sodium perborate. The hydroboration of alkynyl ketones and alkynyl aldehydes with dicyclohexylborane yields the corresponding olefinic carbonyl compounds after protonation, or dicarbonyl compounds after oxidation.