479072-99-6

Basic information

• Product Name: [(diphenylphosphinoethane)PdGe(N(SiMe₃)2)2]2
• Synonyms: [(diphenylphosphinoethane)PdGe(N(SiMe₃)2)2]2
• CAS NO: 479072-99-6
• Molecular Weight: 1796.41
• Mol File: 479072-99-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(diphenylphosphinoethane)PdGe(N(SiMe₃)2)2]2(CAS DataBase Reference)
• NIST Chemistry Reference: [(diphenylphosphinoethane)PdGe(N(SiMe₃)2)2]2(479072-99-6)
• EPA Substance Registry System: [(diphenylphosphinoethane)PdGe(N(SiMe₃)2)2]2(479072-99-6)

Safety Data

• Hazardous Substances Data: 479072-99-6(Hazardous Substances Data)

Upstream product

• 94929-12-1 [(diphenylphosphinoethane)Pd(C₂O₄)] 
• 59863-12-6 bis[bis(trimethylsilyl)amino]germanium(II) 

Downstream Products

• 31277-98-2 bis(bis(1,2-diphenylphosphino)ethane)palladium⁽⁰⁾ 
• 59863-12-6 bis[bis(trimethylsilyl)amino]germanium(II) 

Relevant articles and documents

Synthesis and reactivity of a novel palladium germylene system

The synthesis of three novel Pd germylene complexes is reported. (Ph3P)2PdGe[N(SiMe3)2]2 (1) was synthesized by ligand substitution of (Ph3P)4Pd, whereas (Et3P)PdGe[N(SiMe3)2]2 (2) and {appePdGe[N(SiMe3)2]2}2 (3b) (dppe = (diphenylphosphino)ethane) were synthesized by photolytic reduction of their corresponding phosphine oxalato complexes followed by addition of the germylene ligand. In solution, 3b exists in equilibrium with the monomeric dppePdGe[N(SiMe3)2]2 (3a). The germylene ligand of 2 was found to be 1 order of magnitude more labile than the analogous Pt system and 2 orders of magnitude less labile than the analogous Ni system. The reactivity of these new palladium germylenes toward O2 is described.