479685-96-6

Basic information

• Product Name: meso-3.4-bis-(3-methoxy-phenyl)-adipic acid dimethyl ester
• Synonyms: meso-3.4-bis-(3-methoxy-phenyl)-adipic acid dimethyl ester
• CAS NO: 479685-96-6
• Molecular Weight: 386.445
• Mol File: 479685-96-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: meso-3.4-bis-(3-methoxy-phenyl)-adipic acid dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: meso-3.4-bis-(3-methoxy-phenyl)-adipic acid dimethyl ester(479685-96-6)
• EPA Substance Registry System: meso-3.4-bis-(3-methoxy-phenyl)-adipic acid dimethyl ester(479685-96-6)

Safety Data

• Hazardous Substances Data: 479685-96-6(Hazardous Substances Data)

Upstream product

• 38693-90-2 trans-3-(3-methoxyphenyl)acrylic acid methyl ester 

Relevant articles and documents

Stereoselective hydrocoupling of cinnamic acid esters by electroreduction: Application to asymmetric synthesis of hydrodimers

The electroreduction of Ar-substituted methyl cinnamates in acetonitrile gave all-trans cyclized hydrodimers stereoselectively (58-90% de). In all cases, small amounts (2-symmetric dl-3,4-diaryladipic acids and trans-3,4-diarylcyclopentanones. The chiral auxiliary [(1R)-exo]-3-exo-(diphenylmethyl)borneol, prepared from (1R)-(+)-camphor, was highly effective for the stereoselective hydrocoupling of its cinnamates by electroreduction. From the resulting hydrodimers, (3R,4R)-3,4-diaryladipic acid esters and (3R,4R)-3,4-diarylhexane-1,6-diols were synthesized in 87-95% ee.