4895-47-0

Basic information

• Product Name: Benzene, 1,1',1'',1'''-[1,2-ethenediylidenetetrakis(oxy)]tetrakis-
• CAS NO: 4895-47-0
• Molecular Formula: C26H20O4
• Molecular Weight: 396.442
• Mol File: 4895-47-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1',1'',1'''-[1,2-ethenediylidenetetrakis(oxy)]tetrakis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1',1'',1'''-[1,2-ethenediylidenetetrakis(oxy)]tetrakis-(4895-47-0)
• EPA Substance Registry System: Benzene, 1,1',1'',1'''-[1,2-ethenediylidenetetrakis(oxy)]tetrakis-(4895-47-0)

Safety Data

• Hazardous Substances Data: 4895-47-0(Hazardous Substances Data)

Upstream product

• 115262-01-6 [bromo(difluoro)methyl]-trimethyl-silane 
• 139-02-6 sodium phenoxide 
• 1207426-53-6 1-bromo-8-diphenoxyphosphino naphtalene 
• 81290-20-2 (trifluoromethyl)trimethylsilane 
• 603-35-0 triphenylphosphine 
• 16737-44-3 Orthoameisensaeuretriphenylester 
• 39628-29-0 diphenoxyacetyl chloride 
• 729-89-5 1,1-bisacetic acid 
• 920-66-1 1,1,1,3',3',3'-hexafluoro-propanol 
• 308086-26-2 5,5-dimethyl-2,2-diphenoxy-Δ³-1,3,4-oxadiazoline 
• 60-29-7 diethyl ether 
• 4431-86-1 chlorodiphenoxymethane 
• 591-51-5 phenyllithium 
• 107894-02-0 Diphenoxymethyl-triphenyl-phosphoniumchlorid 

Downstream Products

• 118-79-6 2,4,6-tribromophenol 
• 859979-90-1 diphenoxy-acetic acid phenyl ester 

Relevant articles and documents

Efficient Difluoromethylation of Alcohols Using TMSCF2Br as a Unique and Practical Difluorocarbene Reagent under Mild Conditions

A general method for the efficient difluoromethylation of alcohols using commercially available TMSCF2Br (TMS=trimethylsilyl) as a unique and practical difluorocarbene source is developed. This method allows primary, secondary, and even tertiary alkyl difluoromethyl ethers to be synthesized under weakly basic or acidic conditions. The reaction mainly proceeds through the direct interaction between a neutral alcohol and difluorocarbene, which is different from the difluoromethylation of phenols. Moreover, alcohols containing other moieties that are also reactive toward difluorocarbene can be transformed divergently by using TMSCF2Br. This research not only solves the synthetic problem of difluorocarbene-mediated difluoromethylation of alcohols, it also provides new insights into the different reaction mechanisms of alcohol difluoromethylation and phenol difluoromethylation with difluorocarbene species.

Aryloxy Radicals from Diaryloxydiazirines: α-Cleavage of Diaryloxycarbenes or Excited Diazirines?

(Equation presented) The synthesis of diaryloxydiazirines, precursors to diaryloxycarbenes, is described. Thermolyses of the diazirines afford anticipated carbene products, but photolyses afford both carbenes and aryloxy radicals by α-scission. UV spectra of the carbenes and radicals are observed.