4945-26-0

Basic information

• Product Name: 2-Styrylquinoline
• Synonyms: 2-Styrylquinoline;Nsc77968
• CAS NO: 4945-26-0
• Molecular Formula: C₁₇H₁₃N
• Molecular Weight: 231.29
• Mol File: 4945-26-0.mol
• Article Data: 20

Chemical Properties

• Boiling Point: 387°Cat760mmHg
• Flash Point: 168.7°C
• Appearance: /
• Density: 1.156g/cm³
• Vapor Pressure: 7.58E-06mmHg at 25°C
• Refractive Index: 1.727
• CAS DataBase Reference: 2-Styrylquinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Styrylquinoline(4945-26-0)
• EPA Substance Registry System: 2-Styrylquinoline(4945-26-0)

Safety Data

• Hazardous Substances Data: 4945-26-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C17H13N/c1-2-6-14(7-3-1)10-12-16-13-11-15-8-4-5-9-17(15)18-16/h1-13H

Upstream product

• 100-42-5 styrene 
• 1613-37-2 Quinoline N-oxide 
• 1613-41-8 2-phenethyl-quinoline 
• 91-63-4 2-methylquinoline 
• 100-51-6 benzyl alcohol 
• 100-52-7 benzaldehyde 
• 529-23-7 o-aminobenzaldehyde 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 7647-01-0 hydrogenchloride 
• 38101-94-9 rac-1-phenyl-2-(quinolin-2-yl)ethanol 
• 108-24-7 acetic anhydride 
• 98-87-3 benzylidene dichloride 
• 1780-19-4 1,2,3,4-tetrahydro-2-methylquinoline 

Downstream Products

• 62-23-7 4-nitro-benzoic acid 
• 1613-41-8 2-phenethyl-quinoline 
• 81340-59-2 2,2'-- (2-phenylpropane-1,3-diyl)diquinoline 
• 85291-58-3 4-Benzyl-2-phenyl-2,3,5,6,8,9,10,10a,6a-dekahydro-1H-pyrimidin <3,4-a>chinolin-1,3-dion 
• 85291-57-2 4,4,4a-Trichlor-2-phenyl-2,3,4,4a-tetrahydro-1H-pyrimido<3,4-a>chinolin-1,3-dion 
• 85291-49-2 4-Benzyl-2-phenyl-2,3-dihydro-1H-pyrimido<3,4-a>chinolin-1,3-dion 
• 85291-56-1 2-Phenyl-2,3-dihydro-1H-pyrimido<3,4-a>chinolin-1,3-dion 
• 93-10-7 quinoline-2-carboxylic acid 
• 65-85-0 benzoic acid 
• 133318-11-3 2-Phenyl-3-(chinolin-2-yl)propionsaeureethylester 
• 70779-17-8 6-benzhydryl-3,3,4-triphenyl-5-quinolin-2-yl-3,4-dihydro-pyran-2-one 
• 101583-63-5 2-(2-phenylethyl)-1,2,3,4-tetrahydroquinoline 
• 94463-24-8 2-(α,β-dibromo-phenethyl)-quinoline 
• 36098-50-7 (E)-1-methyl-2-styrylquinolin-1-ium iodide 

Relevant articles and documents

Palladium-catalyzed external-oxidant-free coupling reactions between isoquinoline/quinoline N-oxides with olefins

A convenient and efficient approach for the synthesis of 1-alkenylisoquinolines and 2-alkenylquinolines was developed via palladium-catalyzed coupling reactions between isoquinoline/quinoline N-oxides with olefins under external-oxidant-free conditions. B

Role of Benzylic Deprotonation in Nickel-Catalyzed Benzylic Dehydrogenation

Alkylarenes are readily functionalized via the corresponding benzylic anions. Benzylic anions have been used for a range of catalytic reactions, including Ni-catalyzed dehydrogenation. Interestingly, the employment of Zn(TMP) 2for slow and incomplete deprotonation of the benzylic position was observed. This manuscript describes a preliminary investigation into the deprotonation of heteroarenes and its relationship to Ni-catalyzed benzylic dehydrogenation.

Copper-catalyzed asymmetric silyl addition to alkenyl-substituted N -heteroarenes

Asymmetric conjugate addition of PhMe2SiBPin to a wide range of N-heteroaryl alkenes proceeded in the presence of a copper catalyst coordinated with an easily accessible chiral phosphoramidite ligand to afford useful β-silyl N-heteroarenes in high yields (up to 96%) and excellent enantioselectivities (up to 97% ee).