4946-28-5

Basic information

• Product Name: 2-[(4-methylphenyl)sulfanyl]-1H-benzimidazole
• Synonyms: 2-[(4-methylphenyl)sulfanyl]-1H-benzimidazole
• CAS NO: 4946-28-5
• Molecular Weight: 240.329
• Mol File: 4946-28-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-[(4-methylphenyl)sulfanyl]-1H-benzimidazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(4-methylphenyl)sulfanyl]-1H-benzimidazole(4946-28-5)
• EPA Substance Registry System: 2-[(4-methylphenyl)sulfanyl]-1H-benzimidazole(4946-28-5)

Safety Data

• Hazardous Substances Data: 4946-28-5(Hazardous Substances Data)

Upstream product

• 106-45-6 para-thiocresol 
• 86652-69-9 2-azido-4-(tert-butyl)-1-isocyanobenzene 
• 583-39-1 2,3-dihydrobenzimidazol-2-thione 
• 5720-05-8 4-methylphenylboronic acid 
• 624-31-7 4-tolyl iodide 
• 134469-07-1 Benzimidazol-2-thiol 

Relevant articles and documents

Thio radical-induced denitrogenative annulation of 1-azido-2-isocyanoarenes to construct 2-thiolated benzimidazoles

A method for the synthesis of 2-thiolated benzimidazoles is described starting from thiols and 1-azido-2-isocyanoarenes. The isocyano group works as an acceptor of various thio radicals, followed by denitrogenative annulation of the resulting imidoyl radi

Ligand-Free CuI-Catalyzed Chemoselective S-Arylation of 2-Mercaptobenzimidazole with Aryl Iodides

A practical and efficient strategy for the chemoselective C-S cross-coupling of 2-mercaptobenzimidazole derivatives with a range of substituted aryl iodides is described. Under the optimized conditions of 5 mol% CuI and 100 °C, a variety of S-arylated products were obtained in good to excellent yields (up to 92 %) without the need for assisting ligands.