4965-29-1

Basic information

• Product Name: 2,6-DIMETHYLBENZOQUINONE 4-OXIME
• Synonyms: 2,6-DIMETHYLBENZOQUINONE 4-OXIME;LABOTEST-BB LT00454534;2,6-DIMETHYLBENZOQUINONE 4-OXIME 99%;2,6-Dimethyl-4-hydroxyimino-2,5-cyclohexadien-1-one;m-Xylo-p-quinone 4-oxime
• CAS NO: 4965-29-1
• Molecular Formula: C₈H₉NO₂
• Molecular Weight: 151.16
• Mol File: 4965-29-1.mol
• Article Data: 6

Chemical Properties

• Melting Point: 168-169°C
• Boiling Point: 276.175°C at 760 mmHg
• Flash Point: 120.827°C
• Appearance: /
• Density: 1.161g/cm³
• Vapor Pressure: 0.001mmHg at 25°C
• Refractive Index: 1.546
• BRN: 1941151
• CAS DataBase Reference: 2,6-DIMETHYLBENZOQUINONE 4-OXIME(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-DIMETHYLBENZOQUINONE 4-OXIME(4965-29-1)
• EPA Substance Registry System: 2,6-DIMETHYLBENZOQUINONE 4-OXIME(4965-29-1)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 4965-29-1(Hazardous Substances Data)

Usage

General Description

2,6-DIMETHYLBENZOQUINONE 4-OXIME is a chemical compound that belongs to the quinone oxime family. It is a yellow crystalline solid that is commonly used in the synthesis of pharmaceuticals and organic compounds. This chemical is known for its antioxidant properties and is used as an intermediate in the production of dyes and other organic compounds. It is also used in the manufacturing of pesticides and herbicides. Additionally, 2,6-DIMETHYLBENZOQUINONE 4-OXIME has been studied for its potential use in the treatment of cancer and other diseases due to its ability to inhibit cell growth and provide protective effects against oxidative stress.

InChI:InChI=1/C8H9NO2/c1-5-3-7(9-11)4-6(2)8(5)10/h3-4,11H,1-2H3

Upstream product

• 108-68-9 3,5-Dimethylphenol 
• 87-62-7 2,6-dimethylaniline 
• 527-61-7 2,6-dimethyl-1,4-benzoquinone 
• 576-26-1 2.6-dimethylphenol 

Downstream Products

• 15980-22-0 3,5-dimethyl-4-hydroxyaniline 
• 1243378-07-5 4-[(3-chlorophenyl)aminocarbonyloxyimino]-2,6-dimethylcyclohexa-2,5-dien-1-one 
• 1243378-06-4 2,6-dimethyl-4-[(4-methylphenyl)aminocarbonyloxyimino]cyclohexa-2,5-dien-1-one 
• 1243378-05-3 2,6-dimethyl-4-(phenylaminocarbonyloxyimino)cyclohexa-2,5-dien-1-one 
• 157140-38-0 2,6-dimethyl-1,4-dinitrosobenzene 
• 74709-95-8 2,6-dimethyl-p-dinitrobenzene 

Relevant articles and documents

2,6-Dimethy1-1,4-benzoquinone 4-monooxime

Molecules of the title compound, C8H9NO2, are linked into sheets by a combination of C - H...N, O - H...N and O-H...O hydrogen bonds and C-H...π interactions. The hydrogen bonds are arranged as described by the graph-set r

Synthesis and antidepressant evaluation of three para-benzoquinone mono-oximes and their oxy derivatives

A series of three para-benzoquinone mono-oximes and four oxy-derivatives were prepared and tested for their antidepressant properties. The (4E) oxime of 2-isopropyl-5-methyl-para-benzoquinone (4) and the corresponding 2-diethylamino-ethyl derivative (10)

Catalytic Autoxidation of Benzoquinone Dioximes with Nitrogen Oxides: Steric Effects on the Preparation of Monomeric Dinitrosobenzenes

A convenient catalytic method for the autoxidation of quinone dioximes to dinitrosobenzenes with dioxygen is based on the presence of small amounts of nitrogen oxides.The catalytic cycle is deduced from the facile chemical oxidation of quinone dioxime to dinitrobenzene with stoichiometric amounts of the 1-electron oxidant, nitrosonium-either as the NO+BF4- salt or the disproportionated ion pair NO+NO3- derived from nitrogen dioxide.The regeneration of NO+ occurs by the subsequent oxidation of nitric oxide (NO) with dioxygen to nitrogen dioxide followed by the disproportionation to nitrosonium nitrate in the presence of electron-rich donors.Indeed, dioximes of various p-benzoquinones are shown to be strong reducing agents by transient electrochemistry.Electrochemical oxidation also leads to dinitrosobenzenes in good yields at anodic potentials of ca. 1.3 V.The substitution of p-dinitrosobenzene with bulky alkyl groups stabilizes the monomeric form, which is otherwise extensively associated.