496935-53-6

Basic information

• Product Name: 3,3'-bis{1-(isopropylsulfanyl)-6,7,8,9-tetrahydro-5H-cyclohepta[c]pyridine}
• Synonyms: 3,3'-bis{1-(isopropylsulfanyl)-6,7,8,9-tetrahydro-5H-cyclohepta[c]pyridine}
• CAS NO: 496935-53-6
• Molecular Formula: C26H36N2S2
• Molecular Weight: 440.70744
• Mol File: 496935-53-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,3'-bis{1-(isopropylsulfanyl)-6,7,8,9-tetrahydro-5H-cyclohepta[c]pyridine}(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3'-bis{1-(isopropylsulfanyl)-6,7,8,9-tetrahydro-5H-cyclohepta[c]pyridine}(496935-53-6)
• EPA Substance Registry System: 3,3'-bis{1-(isopropylsulfanyl)-6,7,8,9-tetrahydro-5H-cyclohepta[c]pyridine}(496935-53-6)

Safety Data

• Hazardous Substances Data: 496935-53-6(Hazardous Substances Data)

Upstream product

• 14092-11-6 1-pyrrolidino-1-cycloheptene 
• 354127-93-8 3,3′-bis(isopropylthio)-5,5′-bi(1,2,4-triazine) 

Relevant articles and documents

A facile synthesis of annulated 2,2′-bipyridine ligands with alkylsulfanyl and alkylsulfonyl substituents in the 6 and 6' positions [1]

3,3′-Bis(isopropylsulfanyl)-5,5′-bi-1,2,4-triazine 2 is easily transformed into annulated 2,2′-bipyridines 4 and 6 with fused cycloalkene rings via [4+2]cycloaddition/retro cycloaddition reaction with cyclic enamines 3a-d. Oxidation of 4 and 6 with potassium permanganate under phase transfer catalysis conditions provided a series of the corresponding sulfonyl derivatives 7 and 8.