49695-20-7

Basic information

• Product Name: (CO)3(1,2-bis(diphenylphosphino)ethane)MnCl
• CAS NO: 49695-20-7
• Molecular Weight: 572.846
• Mol File: 49695-20-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (CO)3(1,2-bis(diphenylphosphino)ethane)MnCl(CAS DataBase Reference)
• NIST Chemistry Reference: (CO)3(1,2-bis(diphenylphosphino)ethane)MnCl(49695-20-7)
• EPA Substance Registry System: (CO)3(1,2-bis(diphenylphosphino)ethane)MnCl(49695-20-7)

Safety Data

• Hazardous Substances Data: 49695-20-7(Hazardous Substances Data)

Upstream product

• 39929-21-0 (tetrahydrothiophene)gold(I) chloride 
• 103902-93-8 (CO)3[(C₆H₅)2PCH₂CH₂P(C₆H₅)2]Mn[CCC(CH₃)3] 
• 75-09-2 dichloromethane 
• 10170-69-1 dimanganese decacarbonyl 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 
• 7647-01-0 hydrogenchloride 
• 56-23-5 tetrachloromethane 
• 17100-08-2 fac-tricarbonyl(1,2-bis(diphenylphosphino)ethane)hydridomanganese(I) 
• 133872-67-0 fac-(CO)3(1,2-bis(diphenylphosphino)ethane)Mn(OCH₃) 
• 100-07-2 4-methoxy-benzoyl chloride 
• 133872-72-7 Mn(CO)3(1,2-bis(diphenylphosphino)ethane)(COOCH₃) 
• 37583-89-4 (1,2-bis-diphenylphosphinoethane)tricarbonylmanganese 
• 364046-03-7 (CO)3(1,2-bis(diphenylphosphino)ethane)MnF 
• 7647-14-5 sodium chloride 

Downstream Products

• 145088-67-1 [Mn(CO)4(1,2-bis(diphenylphosphino)ethane)](BF₄) 
• 247939-32-8 fac-[Mn(CO)3(H₂O)(1,2-bis(diphenylphosphino)ethane)](BF₄)*water 
• 247939-39-5 fac-[Mn(CO)3(triphenylphosphino)(1,2-bis(diphenylphosphino)ethane)](BF₄) 

Relevant articles and documents

A novel dimanganese complex linked by an unusually strong hydrogen bond. X-ray structure of the hydrogen-bonded complex and ab initio calculations

In an attempt to prepare the fluoro complex (CO)3(dppe)MnF (3) by treating a CH2Cl2 solution of the aqua complex [(CO)3(dppe)Mn(OH2)]BF4 (1) with NaF(aq), we isolated instead, the dimanganese complex, [(CO)3(dppe)Mn(OH2)FMn(dppe)(CO)3]BF 4 (2). The two moieties, 1 and 3, are held together by an unusually strong O-HF hydrogen bond (OF=2.458(3) ?, HF=1.52 ?) between the aqua ligand on one manganese and the fluoro atom on the other manganese. Using as a simple model the interaction between +Li(H2O) and FLi, the hydrogen bonding distance O-HF was calculated to be; OF=2.443 ?. Authentic 3 was prepared in a homogeneous system using CH2Cl2-soluble [Et4N]F.

One-pot synthesis of fac-[Mn(CO)3(P-P)Cl] from Mn2(CO)10, [P-P] and chlorinated solvents: [P-P] = 1,2-bis(diethylphosphino)ethane (depe), 1,2-bis(diphenylphosphino)ethane (dppe) or 1,3-bis(diphenylphosphino)propane (dppp). The X-ray crystal structure of fac-[Mn(CO)3(depe)Cl]

In a one-pot reaction, the three titled manganese chloride complexes were prepared by refluxing Mn2(CO)10 with (P-P) in 2-chloroethanol for two hours. The new compounds were characterized by IR, 1H NMR, mass spectra and microanalyses. The X-ray crystal structure of fac-Mn(CO)3(depe)Cl is also reported.

A convenient synthesis of the manganese and rhenium alkoxides and phenoxides fac-(CO)3(dppe)MOR (R = CH3, C2H5, C6H5; dppe = 1,2-bis(diphenylphosphino)ethane). X-ray structure of fac-(CO)3(dppe)ReOC6H5

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