496962-20-0

Basic information

• Product Name: Benzenepropanoic acid, a-(acetylthio)-, ethyl ester
• CAS NO: 496962-20-0
• Molecular Formula: C13H16O3S
• Molecular Weight: 252.334
• Mol File: 496962-20-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenepropanoic acid, a-(acetylthio)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanoic acid, a-(acetylthio)-, ethyl ester(496962-20-0)
• EPA Substance Registry System: Benzenepropanoic acid, a-(acetylthio)-, ethyl ester(496962-20-0)

Safety Data

• Hazardous Substances Data: 496962-20-0(Hazardous Substances Data)

Upstream product

• 620-79-1 Ethyl 2-benzylacetoacetate 
• 100-44-7 benzyl chloride 
• 10387-40-3 potassium thioacetate 
• 101308-40-1 ethyl 2-bromo-3-phenylpropionate 

Downstream Products

• 76932-17-7 (S)-2-acetylthio-3-phenylpropanoic acid 
• 404582-98-5 (R)-2-Acetylsulfanyl-3-phenyl-propionic acid ethyl ester 
• 57359-76-9 (2R)-2-(acetylthio)-3-phenylpropanoic acid 

Relevant articles and documents

One-pot synthesis of α-bromoesters and ketones from β-ketoesters and diketones using supported reagents system

A simple and efficient method has been developed for the synthesis of α-bromoesters and ketones from β-ketoesters and diketones in one pot using a supported reagents system, CuBr2/Al2O 3-Na2CO3/Al2O3, in which β-ketoester reacts first with CuBr2/Al2O3 and the product, α-bromo-β-ketoester, reacts with Na 2CO3/Al2O3 to give the final product, α-bromoesters in good yields.