499767-96-3

Basic information

• Product Name: [1-(tert-butyl-dimethyl-silanyloxymethyl)-2-(tert-butyl-diphenyl-silanyloxy)-3-oxo-heptadec-4-enyl]-carbamic acid tert-butyl ester
• Synonyms: [1-(tert-butyl-dimethyl-silanyloxymethyl)-2-(tert-butyl-diphenyl-silanyloxy)-3-oxo-heptadec-4-enyl]-carbamic acid tert-butyl ester
• CAS NO: 499767-96-3
• Molecular Weight: 766.265
• Mol File: 499767-96-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1-(tert-butyl-dimethyl-silanyloxymethyl)-2-(tert-butyl-diphenyl-silanyloxy)-3-oxo-heptadec-4-enyl]-carbamic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [1-(tert-butyl-dimethyl-silanyloxymethyl)-2-(tert-butyl-diphenyl-silanyloxy)-3-oxo-heptadec-4-enyl]-carbamic acid tert-butyl ester(499767-96-3)
• EPA Substance Registry System: [1-(tert-butyl-dimethyl-silanyloxymethyl)-2-(tert-butyl-diphenyl-silanyloxy)-3-oxo-heptadec-4-enyl]-carbamic acid tert-butyl ester(499767-96-3)

Safety Data

• Hazardous Substances Data: 499767-96-3(Hazardous Substances Data)

Upstream product

• 10486-19-8 tridecanal 
• 499767-79-2 [4-tert-butoxycarbonylamino-5-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-2-oxo-pentyl]-phosphonic acid dimethyl ester 

Relevant articles and documents

Facile transformation of 2-azetidinones to unsaturated ketones: Application to the formal synthesis of sphingosine and phytosphingosine

2-Azetidinones were smoothly transformed to unsaturated ketones through the ring opening of activated 2-azetidinone by phosphonate stabilized carbanion and subsequent Horner-Wadsworth-Emmons olefination of the resulting β-ketophosphonates with aldehydes.