501328-06-9Relevant articles and documents
Novel sulfinyl imine ligands for asymmetric catalysis
Schenkel, Laurie B.,Ellman, Jonathan A.
, p. 545 - 548 (2003)
(Matrix presented) A novel class of P,N-sulfinyl imine ligands has been prepared that incorporates chirality solely at sulfur. The Pd complex of ligand 14 catalyzes the allylic alkylation reaction with high enantioselectivity (94%), and the first crystal structure of a Pd-bound sulfinyl imine provides insight into binding mode and origins of stereoselectivity.