5034-21-9

Basic information

• Product Name: 4-Acetylcyclohexanone
• Synonyms: 4-Acetylcyclohexanone;4-acetylcyclohexanone(WXC09093)
• CAS NO: 5034-21-9
• Molecular Formula: C₈H₁₂O₂
• Molecular Weight: 140.18
• Mol File: 5034-21-9.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 141.5-142 °C(Press: 20 Torr)
• Appearance: /
• Density: 1.0570 g/cm3
• CAS DataBase Reference: 4-Acetylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Acetylcyclohexanone(5034-21-9)
• EPA Substance Registry System: 4-Acetylcyclohexanone(5034-21-9)

Safety Data

• Hazardous Substances Data: 5034-21-9(Hazardous Substances Data)

Upstream product

• 22460-53-3 4-isopropenylcyclohexanone 
• 69558-44-7 trans-4-acetoxy-1-cyclohexanol 
• 64-19-7 acetic acid 
• 71-43-2 benzene 
• 556-48-9 1,4-Cyclohexanediol 
• 108-24-7 acetic anhydride 
• 106-87-6 4-vinylcyclohexene dioxide 
• 74852-29-2 4-acetyl-2-(2'-pyrimidylthio)-1-cyclohexanone 
• 118823-95-3 1-diethylphosphoryloxy-4-(1-oxoethyl)-1-cyclohexene 
• 917-64-6 methyl magnesium iodide 
• 69947-09-7 1,4-dioxaspiro<4.5>decane-8-carbonitrile 
• 61692-28-2 1-<(Trimethylsilyl)oxy>-4-acetyl-1-cyclohexene 
• 854724-45-1 1-formyloxy-4-(1-formyloxy-vinyl)-cyclohexene 
• 1855-69-2 1-methoxy-4-(1-methoxy-vinyl)-cyclohexene 

Downstream Products

• 107682-87-1 4-acetoxy-cyclohexanone-(2,4-dinitro-phenylhydrazone) 
• 110-15-6 succinic acid 
• 256352-91-7 3-acetylhexanedioic acid 
• 13482-22-9 4-hydroxycyclohexanone 

Relevant articles and documents

ROMPgel-Supported Triphenylphosphine with Potential Application in Parallel Synthesis

(Equation Presented) ROMPgel-supported triphenylphosphine was synthesized in three steps (67%) from norbornadiene, 4-bromoiodobenzene, and chlorodiphenylphosphine. The supported reagent has a high loading (2.5 mmol/g) and favorable swelling properties in organic solvents. It has been utilized for the conversion of alcohols to halides, the reduction of ozonides, and the isomerization of α,β-acetylenic esters and in the Staudinger reaction. In general, filtration of the resin from the reaction mixtures and evaporation gave the corresponding products in high yield and purity.

THE LEWIS ACID CATALYZED DIELS-ALDER REACTION OF 2-DIETHYLPHOSPHORYLOXY-1,3-BUTADIENE, AN OXYGEN-SUBSTITUTED DIENE OF UNUSUAL STABILITY

The title compound 2 was shown to be a useful oxygen-substituted diene in the Lewis acid catalyzed Diels-Alder reaction.It reacts with a variety of dienophiles under mild conditions with excellent regioselectivity.