503590-24-7

Basic information

• Product Name: 2-Oxazolidinone, 3-(1-hexynyl)-4-phenyl-, (4R)-
• CAS NO: 503590-24-7
• Molecular Formula: C15H17NO2
• Molecular Weight: 243.305
• Mol File: 503590-24-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Oxazolidinone, 3-(1-hexynyl)-4-phenyl-, (4R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Oxazolidinone, 3-(1-hexynyl)-4-phenyl-, (4R)-(503590-24-7)
• EPA Substance Registry System: 2-Oxazolidinone, 3-(1-hexynyl)-4-phenyl-, (4R)-(503590-24-7)

Safety Data

• Hazardous Substances Data: 503590-24-7(Hazardous Substances Data)

Upstream product

• 1119-64-8 1-bromohexyne 
• 90319-52-1 (4R)-phenyl-2-oxazolidinone 
• 1119-67-1 1-iodo-1-hexyne 
• 693-02-7 hex-1-yne 

Relevant articles and documents

Regioselective TfOH-mediated hydroamidation of ynamides with nitriles

A new TfOH-mediated reaction of ynamides with nitriles as nucleophiles has been developed. The reaction works efficiently under mild reaction conditions to afford a new class of α-acylaminoenamides readily via the intermediacy of keteniminium ion. The reaction displays generality and a broad substrates scope. Additionally, the α-acylaminoenamides could be transformed to highly substituted pyridine, 4-aminopyrimidine or isoquinoline cores.

A copper-catalyzed C-N bond formation involving sp-hybridized carbons. A direct entry to chiral ynamides via N-alkynylation of amides

A copper-catalyzed new C-N bond formation involving a sp-hybridized carbon is described here leading to a facile entry for syntheses of chiral ynamides. This direct N-alkynylation of amides should have a significant impact on the future development of synthetic methodologies employing ynamides. Copyright