5038-11-9

Basic information

• Product Name: Morpholine, 4,4'-thiobis-
• CAS NO: 5038-11-9
• Molecular Formula: C8H16N2O2S
• Molecular Weight: 204.293
• Mol File: 5038-11-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Morpholine, 4,4'-thiobis-(CAS DataBase Reference)
• NIST Chemistry Reference: Morpholine, 4,4'-thiobis-(5038-11-9)
• EPA Substance Registry System: Morpholine, 4,4'-thiobis-(5038-11-9)

Safety Data

• Hazardous Substances Data: 5038-11-9(Hazardous Substances Data)

Upstream product

• 110-91-8 morpholine 
• 59939-51-4 N-(morpholinothio)imide 
• 53402-10-1 thiocamphor 
• 2958-89-6 N-(chlorosulfanyl)morpholine 
• 84655-87-8 SS-morpholino 4-toluene(dithioperoxo)sulfonate 
• 104867-40-5 N,N'-thiobis(dibenzoylamine) 
• 104867-39-2 2,2'-thiobis(benzo-1,2-thiazolin-3-one)-1,1,1',1'-tetroxide 

Downstream Products

• 117976-89-3 rabeprazole 
• 13463-40-6 iron pentacarbonyl 
• 129554-55-8 (N,N'-thiobismorpholine) tetracarbonyliron 
• 16131-53-6 N,N'-tetrathiobismorpholine 
• 16131-52-5 dimorpholinotrisulfide 
• 103-34-4 4,4'-dithiodimorpholine 
• 50839-53-7 7-chloro-1-morpholino-3-phenyl-1λ⁴,2,4-benzothiadiazine 
• 15209-56-0 morpholinium morpholidobis(phenylsulfonamido)sulfite 
• 85616-09-7 5-chloro-1-morpholino-3-phenyl-1λ⁴,2,4-benzothiadiazine 
• 85739-21-5 N--S,S-bismorpholinosulphimide 
• 85616-10-0 7-methyl-1-morpholino-3-phenyl-1λ⁴,2,4-benzothiadiazine 
• 85739-22-6 N-(N,2-diphenylacetimidoyl)-S,S-dimorpholinosulphimide 
• 34764-82-4 morpholino p-toluenesulfonyl sulfide 
• 16601-12-0 S-(4-toluenesulfonyl) 4-toluenethiosulfonate 

Relevant articles and documents

Synthesis and reaction of tricyclic tetrathiins and pentathiepins: Novel formation of α-disulfines

Cyclic polysulfanes containing a norbornane skeleton (tetrathiins and pentathiepins) were synthesized by two methods. One is the sulfurization of camphor hydrazone with disulfur dichloride, and the other is the reaction of thiocamphor with disulfur dichloride. The reduction of tetrathiin with LiEt 3BH gave the corresponding dithiol that further reacted with methyl iodide to afford the corresponding methyl sulfide. Reaction of tetrathiin with (Ph3P)2PdCl2 or NiBr2 resulted in the formation of the corresponding dithiolene metal complexes. Tetrathiins were stereoselectively oxidized by m-CPBA to afford the corresponding α-disulfines.

REACTION OF N-HALOGENOIMIDES WITH SULFUR. THIODIIMIDES

The reaction of N-halogenoimides with sulfur leads to the production of thiodiimides.The latter are active sulfur-transferring reagents.

DERIVATIVES OF SULFOXYLIC DIAMIDE

N,N'-Disubstituted sulfur diimides are reduced by the action of thiophenols to N,N'-disubstituted sulfoxylic diamides R1NHSNHR2.Compounds where R1 = R2 = SO2Ar, COPh enter readily into reaction both with retention and with cleavage of the S-N bond.In reaction with secondary amines and CH acids they are "carriers of sulfur." 2,5-Diaroyl-1,2,5-thiadiazolidine-3,4-diones are formed by the successive action of trimethylchlorosilane and oxalyl chloride on the compounds where R1 = R2 = COPh, COC6H4Cl-p.