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50398-29-3

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50398-29-3 Usage

General Description

Methanol, bromo- is a chemical compound with the formula CH3Br. It is a colorless, volatile liquid with a sweet odor, and it is commonly used as a solvent, as a precursor to organic compounds, and in the production of pharmaceuticals and dyes. Methanol, bromo- is also used in the manufacturing of pesticides and as a flame-retardant. It is toxic and flammable, and exposure to high concentrations can result in poisoning, respiratory problems, and skin irritation. It is important to handle and store methanol, bromo- with caution and adhere to proper safety protocols when working with it.

Check Digit Verification of cas no

The CAS Registry Mumber 50398-29-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,0,3,9 and 8 respectively; the second part has 2 digits, 2 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 50398-29:
(7*5)+(6*0)+(5*3)+(4*9)+(3*8)+(2*2)+(1*9)=123
123 % 10 = 3
So 50398-29-3 is a valid CAS Registry Number.

50398-29-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name bromomethanol

1.2 Other means of identification

Product number -
Other names Methanol,bromo

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:50398-29-3 SDS

50398-29-3Synthetic route

formaldehyd
50-00-0

formaldehyd

A

bis(bromomethyl) ether
4497-29-4

bis(bromomethyl) ether

B

bis(bromomethoxy)methane

bis(bromomethoxy)methane

C

bromomethanol
50398-29-3

bromomethanol

Conditions
ConditionsYield
With hydrogen bromide; acetic acid for 0.0833333h;
1-(2-Methoxyphenyl)piperazine
35386-24-4

1-(2-Methoxyphenyl)piperazine

bromomethanol
50398-29-3

bromomethanol

1-(2-hydroxyethyl)-4-(2-methoxyphenyl)piperazine
40004-60-2

1-(2-hydroxyethyl)-4-(2-methoxyphenyl)piperazine

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide
3,4-dihydro-2H-pyran
110-87-2

3,4-dihydro-2H-pyran

bromomethanol
50398-29-3

bromomethanol

2-bromomethoxy-tetrahydro-pyran
199998-50-0

2-bromomethoxy-tetrahydro-pyran

Conditions
ConditionsYield
With Amberlyst 15 In hexane at 25℃; for 3h;
PS-4-(BENZYL-ETHYL-SULFONAMIDE)OCTAFLUORO-BUTANE-1-sulfonyl chloride

PS-4-(BENZYL-ETHYL-SULFONAMIDE)OCTAFLUORO-BUTANE-1-sulfonyl chloride

bromomethanol
50398-29-3

bromomethanol

fluorobromomethane precursor resin

fluorobromomethane precursor resin

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran
C34H36Br2N3(1+)*Br(1-)

C34H36Br2N3(1+)*Br(1-)

bromomethanol
50398-29-3

bromomethanol

C35H38Br2N3O(1+)*Br(1-)

C35H38Br2N3O(1+)*Br(1-)

Conditions
ConditionsYield
With sodium hydroxide
C36H42N3(1+)*Br(1-)

C36H42N3(1+)*Br(1-)

bromomethanol
50398-29-3

bromomethanol

C37H44N3O(1+)*Br(1-)

C37H44N3O(1+)*Br(1-)

Conditions
ConditionsYield
With sodium hydroxide

50398-29-3Upstream product

50398-29-3Relevant articles and documents

An expeditious and efficient bromomethylation of thiols: Enabling bromomethyl sulfides as useful building blocks

Silva-Cuevas, Carolina,Paleo, Ehecatl,León-Rayo, David F.,Lujan-Montelongo, J. Armando

, p. 24654 - 24659 (2018/07/25)

A facile and highly efficient method for the bromomethylation of thiols, using paraformaldehyde and HBr/AcOH, has been developed, which advantageously minimizes the generation of highly toxic byproducts. The preparation of 22 structurally diverse α-bromomethyl sulfides illustrates the chemo-tolerant applicability while bromo-lithium exchange and functionalization sequences, free radical reductions, and additions of the title compounds demonstrate their synthetic utility.

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