5056-00-8

Basic information

• Product Name: (3S,6R)-3-methyl-6-(1-methylethyl)cyclohexene
• Synonyms: (3S,6R)-3-methyl-6-(1-methylethyl)cyclohexene
• CAS NO: 5056-00-8
• Molecular Weight: 138.253
• Mol File: 5056-00-8.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (3S,6R)-3-methyl-6-(1-methylethyl)cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,6R)-3-methyl-6-(1-methylethyl)cyclohexene(5056-00-8)
• EPA Substance Registry System: (3S,6R)-3-methyl-6-(1-methylethyl)cyclohexene(5056-00-8)

Safety Data

• Hazardous Substances Data: 5056-00-8(Hazardous Substances Data)

Upstream product

• 491-07-6 isomenthone 
• 73316-48-0 Acetic acid (1S,6R)-6-isopropyl-cyclohex-2-enyl ester 
• 917-64-6 methyl magnesium iodide 
• 99-87-6 4-methylisopropylbenzene 
• 5055-99-2 (+)-(1S,2S,5S)-carvomenthyl tosylate 
• 15356-60-2 (1S,2R,5S)-(+)-menthol 
• 491-04-3 trans-6-isopropyl-3-methylcyclohex-2-en-1-ol 
• 554-61-0 3,7,7-trimethylbicyclo[4.1.0]hept-2-ene 
• 63296-63-9 cis-(+/-)-(1R,6SR)-6-isopropyl-2-cyclohexen-1-ol 
• 4705-06-0 (+/-)-1r-Isopropyl-cyclohexen-⁽²⁾-ol-(4t) 
• 63296-63-9 trans-(+/-)-(1R,6R)-6-isopropyl-2-cyclohexen-1-ol 
• 83670-70-6 Acetic acid (1S,4R)-4-isopropyl-cyclohex-2-enyl ester 
• 75-24-1 trimethylaluminum 

Downstream Products

• 3804-01-1 (1RS,2SR,3RS,4RS)-p-menthane-2,3-diol 
• 3804-01-1 (1RS,2SR,3SR,4RS)-p-menthane-2,3-diol 
• 3804-01-1 (1RS,2RS,3RS,4RS)-p-menthane-2,3-diol 

Relevant articles and documents

M -C2B10H11HgCl/AgOTf-Catalyzed Reaction for Reductive Deoxygenation

A m -C2B10H11HgCl/AgOTf-catalyzed reaction of allyl silyl ethers with N -Boc- N ′-tosylhydrazine has been developed. Under mild conditions, the resulting allyl hydrazine products were transformed into naked alkenes in good yield. Furthermore, the used m -C2B10H11HgCl could be recovered quantitatively.

Radical chain reduction of alkylboron compounds with catechols

The conversion of alkylboranes to the corresponding alkanes is classically per-formed via protonolysis of alkylboranes. This simple reaction requires the use of severe reaction conditions, that is, treatment with a carboxylic acid at high temperature (>150 °C). We report here a mild radical procedure for the transformation of organoboranes to alkanes. 4-tert-Butylcatechol, a well-established radical inhibitor and antioxidant, is acting as a source of hydrogen atoms. An efficient chain reaction is observed due to the exceptional reactivity of phenoxyl radicals toward alkylboranes. The reaction has been applied to a wide range of organoboron derivatives such as B- alkylcatecholboranes, trialkylboranes, pinacolboronates, and alkylboronic acids. Furthermore, the so far elusive rate constants for the hydrogen transfer between secondary alkyl radical and catechol derivatives have been experimentally determined. Interestingly, they are less than 1 order of magnitude slower than that of tin hydride at 80 °C, making catechols particularly attractive for a wide range of transformations involving C-C bond formation.

Copper-Mediated and -Catalyzed o-DPPB-Directed Allylic Substitution

Complete control of chemo-, regio- and stereoselectivity in the course of copper-catalyzed and -mediated allylic substitution could be obtained with me ortho-diphenylphosphanyl (o-DPPB) function as a reagent-directing leaving group. Complete chirality transfer by way of a syn-addition process has been achieved for cyclic and acyclic systems. Readily available Grignard reagents may be employed as nucleophiles and the directing o-DPPB group can be recovered quantitatively. The reaction requires neither cooling nor an excess of organometallic reagent.