50625-52-0

Basic information

• Product Name: Benzoic acid, 2-bromo-, 2-phenylhydrazide
• CAS NO: 50625-52-0
• Molecular Formula: C13H11BrN2O
• Molecular Weight: 291.147
• Mol File: 50625-52-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-bromo-, 2-phenylhydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-bromo-, 2-phenylhydrazide(50625-52-0)
• EPA Substance Registry System: Benzoic acid, 2-bromo-, 2-phenylhydrazide(50625-52-0)

Safety Data

• Hazardous Substances Data: 50625-52-0(Hazardous Substances Data)

Upstream product

• 100-63-0 phenylhydrazine 
• 88-65-3 2-bromobenzoic-acid 
• 88562-26-9 2-bromobenzoyl cyanide 
• 60-29-7 diethyl ether 
• 7154-66-7 2-bromobenzoic acid chloride 

Downstream Products

• 1370643-32-5 5-phenylindazolo[3,2-b]quinazolin-7(5H)-one 
• 588-59-0 stilbene 
• 28561-80-0 1-phenyl-1,2-dihydro-3H-indazol-3-one 
• 17049-65-9 2-phenyl-1,2-dihydro-3H-indazol-3-one 
• 69660-01-1 o-bromobenzoyl chloride phenylhydrazone 
• 857796-71-5 N'-(2-bromo-benzoyl)-N-chloroacetyl-N-phenyl-hydrazine 

Relevant articles and documents

A [4 + 3] Annulation Reaction of aza- o-Quinone Methides with Arylcarbohydrazonoyl Chlorides for Synthesis of 2,3-Dihydro-1 H-benzo[ e][1,2,4]triazepines

An unprecedented [4 + 3] annulation reaction of aza-ortho-quinone methides with arylcarbohydrazonoyl chlorides has been achieved under mild conditions. The annulation underwent a sequential conjugate addition/intramolecular annulation/rearrangement, providing a useful method for the synthesis of biologically interesting 2,3-dihydro-1H-benzo[e][1,2,4]triazepine.

Copper-catalyzed synthesis of substituted indazoles from 2-chloroarenes at low catalyst-loading

An efficient and convenient access to 1-substituted indazol-3-ones 2 has been achieved throughout the intramolecular C-N bond formations of 2-chloro-benzoic acid-N′-aryl and alkyl-hydrazides employing 0.5 mol% of cuprous (I) iodide and 20 mol% of l-prolin