50628-92-7

Basic information

• Product Name: ETHYL 6-KETO-7-OCTENOATE
• Synonyms: ETHYL 6-KETO-7-OCTENOATE
• CAS NO: 50628-92-7
• Molecular Formula: C₁₀H₁₆O₃
• Molecular Weight: 184.23
• Product Categories: pharmacetical
• Mol File: 50628-92-7.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 253.8°C at 760 mmHg
• Flash Point: 104.7°C
• Appearance: /
• Density: 0.973g/cm³
• Vapor Pressure: 0.0179mmHg at 25°C
• Refractive Index: 1.44
• CAS DataBase Reference: ETHYL 6-KETO-7-OCTENOATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL 6-KETO-7-OCTENOATE(50628-92-7)
• EPA Substance Registry System: ETHYL 6-KETO-7-OCTENOATE(50628-92-7)

Safety Data

• Hazardous Substances Data: 50628-92-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H16O3/c1-3-9(11)7-5-6-8-10(12)13-4-2/h3H,1,4-8H2,2H3

Upstream product

• 1071-71-2 ethyl 6-chloro-6-oxohexanoate 
• 74-85-1 ethene 
• 41302-32-3 ethyl 5-iodopentanoate 
• 814-68-6 acryloyl chloride 
• 14660-52-7 ethyl 5-bromovalerate 

Downstream Products

• 101253-69-4 6-oxo-8-phenoxy-octanoic acid ethyl ester 
• 408333-41-5 8-benzylsulfanyl-6-oxo-octanoic acid 
• 53342-16-8 chlamydocin 
• 88568-94-9 (5S,11R,13aR)-5-Benzyl-11-{5-[2-(2-chloro-ethyl)-[1,3]dioxolan-2-yl]-pentyl}-8,8-dimethyl-decahydro-3a,6,9,12-tetraaza-cyclopentacyclododecene-4,7,10,13-tetraone 
• 88568-94-9 (5S,11S,13aR)-5-Benzyl-11-{5-[2-(2-chloro-ethyl)-[1,3]dioxolan-2-yl]-pentyl}-8,8-dimethyl-decahydro-3a,6,9,12-tetraaza-cyclopentacyclododecene-4,7,10,13-tetraone 
• 52574-63-7 (5S,11S,13aR)-5-Benzyl-8,8-dimethyl-11-(6-oxo-oct-7-enyl)-decahydro-3a,6,9,12-tetraaza-cyclopentacyclododecene-4,7,10,13-tetraone 
• 89525-27-9 (E)-2-Benzyloxycarbonylamino-7-[2-(2-chloro-ethyl)-[1,3]dioxolan-2-yl]-hept-2-enoic acid methyl ester 
• 88568-93-8 (R)-1-[(S)-2-(2-{(R)-2-Benzyloxycarbonylamino-7-[2-(2-chloro-ethyl)-[1,3]dioxolan-2-yl]-heptanoylamino}-2-methyl-propionylamino)-3-phenyl-propionyl]-pyrrolidine-2-carboxylic acid pentafluorophenyl ester 
• 88568-93-8 (R)-1-[(S)-2-(2-{(S)-2-Benzyloxycarbonylamino-7-[2-(2-chloro-ethyl)-[1,3]dioxolan-2-yl]-heptanoylamino}-2-methyl-propionylamino)-3-phenyl-propionyl]-pyrrolidine-2-carboxylic acid pentafluorophenyl ester 
• 88568-92-7 2-Benzyloxycarbonylamino-7-[2-(2-chloro-ethyl)-[1,3]dioxolan-2-yl]-heptanoic acid 
• 101577-56-4 8-benzyloxy-6-oxo-octanoic acid ethyl ester 
• 107524-25-4 8-benzylsulfanyl-6-oxo-octanoic acid ethyl ester 

Relevant articles and documents

Enantioselective allylic hydroxylation of w-alkenoic acids and esters by P450 BM3 monooxygenase

Chiral allylic alcohols of w-alkenoic acids and derivatives thereof are highly important building blocks for the synthesis of biologically active compounds. The direct enantioselective C-H oxidation of linear terminal olefins offers the shortest route toward these compounds, but known synthetic methods are limited and suffer from low selectivities. Described herein is an enzymatic approach using the P450 BM3 monooxygenase mutant A74G/L188Q, which catalyzes allylic hydroxylation with high to excellent chemo- and enantioselectivities providing the desirable secondary alcohols.