50816-18-7

Basic information

• Product Name: ACETIC ACID 9-DECEN-1-YL ESTER
• Synonyms: Acetic acid 9-decenyl ester;aceticacid,9-decenylester;aceticaciddecenylester;Decenyl acetate;decenylacetate;9-DECEN-1-OL ACETATE;9-DECEN-1-YL ACETATE;9-DECENYL ACETATE
• CAS NO: 50816-18-7
• Molecular Formula: C₁₂H₂₂O₂
• Molecular Weight: 198.3
• EINECS: 256-784-1
• Mol File: 50816-18-7.mol
• Article Data: 24

Chemical Properties

• Boiling Point: 246°C
• Appearance: /
• Density: 0,88 g/cm3
• Refractive Index: 1.4350-1.4380
• CAS DataBase Reference: ACETIC ACID 9-DECEN-1-YL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: ACETIC ACID 9-DECEN-1-YL ESTER(50816-18-7)
• EPA Substance Registry System: ACETIC ACID 9-DECEN-1-YL ESTER(50816-18-7)

Safety Data

• Safety Statements: 24/25
• RTECS: AG5230000
• Hazardous Substances Data: 50816-18-7(Hazardous Substances Data)

Usage

Safety Profile

Low toxicity by ingestion and skin contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

Upstream product

• 13019-22-2 9-Decen-1-ol 
• 581-55-5 benzylidene 1,1-diacetate 
• 25601-41-6 methyl 9-decenoate 
• 53463-68-6 1-bromo-10-decanol 
• 143-28-2 oleoyl alcohol 
• 693-80-1 oleyl acetate 
• 112-47-0 1,10-Decanediol 
• 112-19-6 10-undecenyl acetate 
• 54894-30-3 11-acetoxyundecanoic acid 
• 85576-11-0 C₁₃H₂₅LiO₂ 
• 75-36-5 acetyl chloride 
• 74-86-2 acetylene 
• 56904-95-1 (bromo-8 octyloxy-1)-1, ethoxy-1 ethane 
• 85576-23-4 1-Chloro-8-(1-ethoxy-ethoxy)-octane 

Downstream Products

• 33189-72-9 (E)-tetradec-11-en-1-yl acetate 
• 19754-58-6 2-dec-9-ynyloxy-tetrahydro-pyran 
• 60037-69-6 9-tetradecyn-1-ol 
• 16725-53-4 (Z)-9-tetradecen-1-yl acetate 
• 17643-36-6 9-decyn-1-ol 
• 88109-73-3 9-hexadecyn-1-ol 
• 19754-59-7 tetrahydro-2-(9-tetradecynyloxy)pyran 
• 1286209-77-5 C₂₂H₃₄O₅ 
• 106-98-9 1-butylene 
• 16974-34-8 Δ⁹-Dodecenyl acetate 
• 57568-18-0 diacetoxy-1,8 octadecene-9 
• 693-80-1 oleyl acetate 
• 16974-11-1 (Z)-9-dodecenyl acetate 
• 1471573-78-0 C₃₅H₃₇NO₂P⁽¹⁺⁾*Br^(1-) 

Relevant articles and documents

New SF5-long chain carbon systems

A new SF5-terminated perfluoroalkyl thiol - SF5(CF2)6CH2CH2SH - and a symmetric SF5-terminated dialkyl disulfide - [SF5CH-CH(CH2)8S]2 - were synthesized from the corresponding SF5-terminated precursors. The chemistry employed in the preparation of the disulfide encompasses high yield pathways for the preparation of new SF5-long chain derivatives.

Amine-borane complex-initiated SF5Cl radical addition on alkenes and alkynes

The SF5Cl radical addition on unsaturated compounds was performed using an air-stable amine-borane complex as the radical initiator. This method showed to be complementary to the classic Et3B-mediated SF5Cl addition on alkenes and alkynes. A total of seven alkene and three alkyne derivatives were tested in the reaction, with yields ranging from 3% to 85%.

PRODUCTION OF FATTY OLEFIN DERIVATIVES VIA OLEFIN METATHESIS

In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.