50870-65-0

Basic information

• Product Name: bis(benzyloxy)diphenylsilane
• Synonyms: bis(benzyloxy)diphenylsilane
• CAS NO: 50870-65-0
• Molecular Weight: 396.561
• Mol File: 50870-65-0.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: bis(benzyloxy)diphenylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: bis(benzyloxy)diphenylsilane(50870-65-0)
• EPA Substance Registry System: bis(benzyloxy)diphenylsilane(50870-65-0)

Safety Data

• Hazardous Substances Data: 50870-65-0(Hazardous Substances Data)

Upstream product

• 775-12-2 diphenylsilane 
• 100-51-6 benzyl alcohol 
• 80-10-4 diphenylsilyl dichloride 
• 100-52-7 benzaldehyde 

Downstream Products

• 947-42-2 diphenylsilanediol 
• 797-77-3 1,1,1,5,5,5-hexamethyl-3,3-diphenyltrisiloxane 
• 108-88-3 toluene 

Relevant articles and documents

Cooperative metal-ligand reactivity and catalysis in low-spin ferrous alkoxides

This report describes examples of combined Fe- and O-centered reactivity of Fe(P2O2)(CO)2 (1), where P2O2 is the diphosphinoglycolate (Ph2PC6H4CHO)22-

N-Heterocyclic Carbene Complexes of Nickel, Palladium, and Iridium Derived from Nitron: Synthesis, Structures, and Catalytic Properties

The mesoionic compound (1,4-diphenyl-1,2,4-triazol-4-ium-3-yl)phenylazanide, commonly referred to as Nitron, has been employed as a "crypto-NHC"to afford 1,2,4-triazolylidene compounds of nickel, palladium, and iridium. Specifically, Nitron reacts with NiBr2, PdCl2, and [Ir(COD)Cl]2 to afford the N-heterocyclic carbene complexes (NitronNHC)2NiBr2, (NitronNHC)2PdCl2, and (NitronNHC)Ir(COD)Cl, respectively. The lattermost compound reacts with (i) CO to afford the dicarbonyl compound (NitronNHC)Ir(CO)2Cl and (ii) CO, in the presence of PPh3, to afford the monocarbonyl compound (NitronNHC)Ir(PPh3)(CO)Cl. Structural studies on (NitronNHC)Ir(COD)Cl and (NitronNHC)Ir(CO)2Cl indicate that NitronNHC has a stronger trans influence than does Cl; furthermore, IR spectroscopic studies on (NitronNHC)Ir(CO)2Cl indicate that NitronNHC is electronically similar to the structurally related Enders carbene but is less electron donating than imidazol-2-ylidenes with aryl substituents. Significantly, the NitronNHC ligand affords catalytic systems, as illustrated by the ability of (NitronNHC)Ir(CO)2Cl to effect (i) the dehydrogenation of formic acid, (ii) aldehyde hydrosilylation, (iii) dehydrocoupling of hydrosilanes and alcohols, and (iv) ketone reduction via transfer hydrogenation.

Photoactivated silicon-oxygen and silicon-nitrogen heterodehydrocoupling with a commercially available iron compound

Silicon-oxygen and silicon-nitrogen heterodehydrocoupling catalyzed by the commercially available cyclopentadienyl dicarbonyl iron dimer [CpFe(CO)2]2 (1) under photochemical conditions is reported. Reactions between alcohols and PhSi