50895-59-5 Usage
Description
Decahydrotricyclopropa[cd,f,hi]indene is a tricyclic hydrocarbon chemical compound with the molecular formula C11H14. It features a unique fused three-ring system composed of three cyclopropane rings. This colorless liquid exhibits a strong, petroleum-like odor and is utilized in various industrial applications.
Uses
Used in Chemical Synthesis:
Decahydrotricyclopropa[cd,f,hi]indene serves as a solvent and is used in the synthesis of organic molecules. Its tricyclic structure makes it a versatile component in creating complex organic compounds.
Used in Polymer and Resin Production:
It is a valuable building block for the production of various polymers and resins. Its unique structure contributes to the formation of polymers with specific properties required in different industries.
Used as a Chemical Intermediate:
Decahydrotricyclopropa[cd,f,hi]indene is used as a chemical intermediate for the development of pharmaceuticals and agricultural products. Its role in these industries is crucial for creating effective and innovative solutions.
Safety Precautions:
It is important to handle decahydrotricyclopropa[cd,f,hi]indene with care and in a well-ventilated area due to its strong odor and potential health hazards. Proper handling ensures the safety of individuals working with this chemical compound.
Check Digit Verification of cas no
The CAS Registry Mumber 50895-59-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,0,8,9 and 5 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 50895-59:
(7*5)+(6*0)+(5*8)+(4*9)+(3*5)+(2*5)+(1*9)=145
145 % 10 = 5
So 50895-59-5 is a valid CAS Registry Number.
50895-59-5Relevant articles and documents
Diademane and Structurally Related Compounds, I. Preparation and Characteristic Reactions of Some Tris-?-homobenzene Hydrocarbons
Kaufmann, Dieter,Fick, Hans-Heinrich,Schallner, Otto,Spielmann, Werner,Meyer, Lueder-Ulrich,et al.
, p. 587 - 609 (2007/10/02)
Diademane (5) and 1,6-Homodiademane (6) are the first hydrocarbons with cis-tris-?-homobenzene skeletons.They were prepared by photoisomerization of the olefinic precursors 8 (snoutene) and 15 (4,5-homosnoutene), respectively.In an analogous reaction the bridged trans-tris-?-homobenzene 7 was formed from 17 (endo,exo-bishomobarrelene). 7 is more easily obtained from 17 by rhodium(I)-catalyzed isomerization or from exo,exo-bishomobarrelene 18 by thermal rearrangement.The unbridged 4 was prepared using a newly developed synthetic sequence starting from 1,3-cyclohexadiene.The thermal rearrangement of 5 and 6 to triquinancene (9) and 1,10-homotriquinancene (16) is very facile; the gas phase kinetic parameters (ln k (5) = 33.7 - 31600/RT and ln k (6) = 32.2 - 28300/RT, both first order) strongly corroborate, that these rearrangements are concerted ?2S + ?2S + ?2S> cycloreversions. -labelled 4 upon thermolysis yields a trans-bicyclonona-3,7-diene (31 22) with a 12C-labelling pattern, which proves its formation via a 3-step mechanism.The first step in this sequence most probably is a ?2S + ?2S + ?2S> cycloreversion with ln k = 30.8 - 42000/RT (first order).Only the bridged compound 7 does not follow the sample path, probably due to excessive ring strain in the transition state, and prefers a stepwise cycloreversion leading to 18 and at least 5 secondary products.