51075-25-3

Basic information

• Product Name: (E)/(Z)-Trimethylsiloxymethylene-3-cyclohexene
• Synonyms: (E)/(Z)-Trimethylsiloxymethylene-3-cyclohexene
• CAS NO: 51075-25-3
• Molecular Weight: 182.338
• Mol File: 51075-25-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)/(Z)-Trimethylsiloxymethylene-3-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)/(Z)-Trimethylsiloxymethylene-3-cyclohexene(51075-25-3)
• EPA Substance Registry System: (E)/(Z)-Trimethylsiloxymethylene-3-cyclohexene(51075-25-3)

Safety Data

• Hazardous Substances Data: 51075-25-3(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 

Downstream Products

• 1121-54-6 1,3-Cyclohexadiene-1-carbaldehyde 
• 58836-15-0 1,4-cyclohexadiene-1-carboxaldehyde 
• 55638-24-9 1-(acetyloxy)-3-cyclohexenecarboxaldehyde 
• 55638-21-6 3-Chloro-benzoic acid (1-hydroxy-cyclohex-3-enyl)-trimethylsilanyloxy-methyl ester 
• 59679-11-7 Dimethyl-dithiocarbamic acid 1-formyl-cyclohex-3-enyl ester 

Relevant articles and documents

A Solvent-Free Reaction for Silyl Enol Ethers Synthesis

Silyl enol ethers are extremely useful nucleophilic intermediates for chemical transformations because they are synthetically versatile substrates for a wide range of C-C bond-forming reactions. Here, we present a new, mild, and solvent-free procedure for the synthesis of silyl enol ethers that employs a catalytic amount of solid-supported base and an equimolar amount of N, O -(bistrimethylsilyl)acetamide as a silylating agent.