5113-93-9

Basic information

• Product Name: (+)-TRANS-P-MENTH-2-ENE
• Synonyms: (3S,6R)-3-ISOPROPYL-6-METHYLCYCLOHEXENE;(+)-TRANS-P-MENTH-2-ENE;(3S,6R)-3-isopropyl-6-Methylcyclohex-1-ene
• CAS NO: 5113-93-9
• Molecular Formula: C₁₀H₁₈
• Molecular Weight: 138.25
• Mol File: 5113-93-9.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 55-56 °C12 mm Hg(lit.)
• Flash Point: 48 °C
• Appearance: /
• Density: 0.811 g/mL at 20 °C(lit.)
• Vapor Pressure: 2.49mmHg at 25°C
• Refractive Index: n20/D 1.450
• BRN: 2037958
• CAS DataBase Reference: (+)-TRANS-P-MENTH-2-ENE(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-TRANS-P-MENTH-2-ENE(5113-93-9)
• EPA Substance Registry System: (+)-TRANS-P-MENTH-2-ENE(5113-93-9)

Safety Data

• Statements: 10
• Safety Statements: 16
• RIDADR: UN 2319 3/PG 3
• WGK Germany: 3
• F: 10-23
• Hazardous Substances Data: 5113-93-9(Hazardous Substances Data)

Usage

General Description

(+)-TRANS-P-MENTH-2-ENE is a chemical compound and a terpene that belongs to the class of cyclic monoterpenes. It has a characteristic minty and herbal aroma and is commonly found in essential oils of various plants, including mint, parsley, and basil. It is used in the food and beverage industry as a flavoring agent and is also employed in the fragrance and cosmetic industries. (+)-TRANS-P-MENTH-2-ENE is known for its potential therapeutic properties, including its anti-inflammatory and analgesic effects, and is being studied for its potential as a natural remedy for various health conditions. Additionally, it is often used in organic synthesis as a precursor for the production of other chemicals and compounds.

InChI:InChI=1/C10H18/c1-8(2)10-6-4-9(3)5-7-10/h4,6,8-10H,5,7H2,1-3H3/t9-,10-/m0/s1

Upstream product

• 93919-01-8 stearic acid-((1R)-menthyl ester) 
• 99-87-6 4-methylisopropylbenzene 
• 5113-87-1 3-methyl-6-(prop-1-en-2-yl)cyclohexene 
• 2552-91-2 (1S)-(+)-neomenthol acetate 
• 2216-51-5 (-)-menthol 
• 100386-93-4 dimethyl-((1R)-neomenthyl)-amine oxide 
• 60965-62-0 thiocarbonic acid O-((1R)-menthyl ester)-S-methyl ester 
• 108991-79-3 (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl methyl carbonate 
• 13371-12-5 neomenthyl chloride 
• 141-52-6 sodium ethanolate 
• 16052-42-9 (1R,2S,5R)-menthyl chloride 
• 64-17-5 ethanol 
• 491-04-3 trans-6-isopropyl-3-methylcyclohex-2-en-1-ol 
• 554-61-0 3,7,7-trimethylbicyclo[4.1.0]hept-2-ene 

Downstream Products

• 1678-82-6 trans-1,4-menthane 
• 308355-91-1 ((1S,2R,35,6R)-2-hydroxy-3-isopropyl-6-methyl-cyclohexanol) 
• 64839-29-8 (1R,2S,3R,6S)-3-methyl-6-(methylethyl)cyclohexane-1,2-diol 
• 140924-67-0 (1S,2S,3R,6S)-3-methyl-6-(methylethyl)cyclohexane-1,2-diol 
• 102748-64-1 (1R,2S,3S,4S)-2,3-bis-(3,5-dinitro-benzoyloxy)-p-menthane 
• 112506-98-6 (1R,2S,3R,4S)-3-(3,5-dinitro-benzoyloxy)-p-menthan-2-ol 
• 308355-90-0 (1R,2R,3R,6S)-3-methyl-6-(methylethyl)cyclohexane-1,2-diol 
• 61585-35-1 p-menth-1-ene 
• 500-00-5 3-p-menthene 
• 99-82-1 Menthane 
• 99-87-6 4-methylisopropylbenzene 
• 1845-56-3 Diacetat aus (+)-p-Menthan-2,3-diol 
• 1753-38-4 2t-Acetoxy-3t-isopropyl-6c-methyl-cyclohexan-1r-ol 
• 3804-01-1 (1RS,2SR,3RS,4RS)-p-menthane-2,3-diol 

Relevant articles and documents

1,2-Dibromotetrachloroethane: An efficient reagent for many transformations by modified Appel reaction

An efficient and facile method has been developed for the synthesis of alkyl bromides from various alcohols under mild conditions using a triphenylphosphine (PPh 3) /1,2-dibromotetrachloroethane (DBTCE) complex in excellent yields and very short time (5 min). This method can also be applied for the transformation of chiral alcohols to their corresponding bromides in very high enantiomeric excess. The PPh 3 /DBTCE complex is also successfully applied to ring-opening reactions of cyclic ethers in mild conditions. Esterification, amidation, and formation of acid anhydrides under very mild experimental conditions are also successfully accomplished by following a modification of the Appel reaction protocol in this work.

M -C2B10H11HgCl/AgOTf-Catalyzed Reaction for Reductive Deoxygenation

A m -C2B10H11HgCl/AgOTf-catalyzed reaction of allyl silyl ethers with N -Boc- N ′-tosylhydrazine has been developed. Under mild conditions, the resulting allyl hydrazine products were transformed into naked alkenes in good yield. Furthermore, the used m -C2B10H11HgCl could be recovered quantitatively.

Synthesis and sensory studies of umami-active scaffolds

The class of 2-isopropyl-5-methylbicyclo[4.1.0]heptane-7-carboxamides, 1-4, has been identified as potent umami-tasting molecules. A scalable synthesis of this challenging scaffold and new sensory insights will be presented. Interestingly, the umami chara