51142-88-2Relevant articles and documents
Formation and calculations of the simple terminal triplet pnictinidene molecules n÷MF3, P÷MF3, and As÷MF3 (M = Ti, Zr, Hf)
Wang, Xuefeng,Lyon, Jonathan T.,Andrews, Lester
, p. 6297 - 6302 (2009/12/04)
Laser-ablated Ti, Zr, and Hf atoms react with NF3, PF 3, or AsF3 to produce triplet state terminal pnictinidene N÷MF3, P÷MF3, or As÷MF3 molecules, which are trapped in an argon matrix. Prod
The pure rotational spectrum of TiF (X4Φr): 3 d transition metal fluorides revisited
Sheridan,McLamarrah,Ziurys
, p. 9496 - 9503 (2007/10/03)
The first measurement of the pure rotational spectrum of the TiF radical using millimeter/sub-mm direct absorption methods is presented. The given data is modeled using a Hund's case (a) effective Hamiltonian, leading to the determination of rotational, fine structure, and hyperfine parameters. This paper presents the results, interpret the constants and discuss their implications for bonding in 3d transition metal fluorides.