51146-39-5

Basic information

• Product Name: trimethylsilyl ester of aci-nitrophenylmethane
• Synonyms: trimethylsilyl ester of aci-nitrophenylmethane
• CAS NO: 51146-39-5
• Molecular Weight: 209.32
• Mol File: 51146-39-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: trimethylsilyl ester of aci-nitrophenylmethane(CAS DataBase Reference)
• NIST Chemistry Reference: trimethylsilyl ester of aci-nitrophenylmethane(51146-39-5)
• EPA Substance Registry System: trimethylsilyl ester of aci-nitrophenylmethane(51146-39-5)

Safety Data

• Hazardous Substances Data: 51146-39-5(Hazardous Substances Data)

Upstream product

• 622-42-4 1-nitro-1-phenylmethane 
• 10416-58-7 N,N-bis(trimethylsilyl)acetamide 
• 75-77-4 chloro-trimethyl-silane 
• 100-39-0 benzyl bromide 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 

Downstream Products

• 133706-01-1 ((1S,5R,7R)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-(3-phenyl-2-trimethylsilanyloxy-isoxazolidin-5-yl)-methanone 
• 20408-11-1 (E)-N,N-dimethyl-2-nitro-2-phenylethenamine 
• 119897-84-6 ((3aS,6R,7aR)-8,8-dimethyl-2,2-dioxidohexahydro-1H-3a,6-methanobenzo[c]isothiazol-1-yl)((S)-3-phenyl-4,5-dihydroisoxazol-5-yl)methanone 
• 119897-84-6 ((3aS,6R,7aR)-8,8-dimethyl-2,2-dioxidohexahydro-1H-3a,6-methanobenzo[c]isothiazol-1-yl)((R)-3-phenyl-4,5-dihydroisoxazol-5-yl)methanone 
• 201024-81-9 C,N-diphenylnitrone 
• 106808-15-5 3-phenyl-5-<(phenylsulfonyl)methyl>isoxazole 

Relevant articles and documents

Reactions of silyl nitronates with dimethylformamide dimethyl acetal as a new general procedure for the synthesis of 2-nitroenamines

Silyl nitronates obtained in situ from the corresponding aliphatic nitro compounds react with dimethylformamide dimethyl acetal giving 2-nitroenamines in moderate to good yields. The reaction pathway is discussed.

Asymmetric silyl nitronate cycloadditions with bornane-10,2-sultam derivatives

Asymmetric silyl nitronate cycloadditions with N-acryloyl (2R)-bornane-10,2-sultam, N-acryloyl (2S)-bornane-10,2-sultam, and N-methacryloyl (2R)-bornane-10,2-sultam have been studied. The asymmetric silyl nitronate cycloaddition/elimination methodology pr

Reactions of Trialkylsilyl Trifluoromethanesulfonates, IV. - 1,3-Trialkylsiloxy Shift - a New Rearrangement Reaction During the Silylation of Nitroalkanes

Nitroalkanes 1 with C-H bonds in β-position react with two-fold molar amounts of trialkylsilyl triflates 2 in the presence of triethylamine to yield 2-(trialkylsiloxy)oxime O-trialkylsilyl ethers 5 by 1,3-trialkylsiloxy shift.Oxime ethers 5 are also obtai