5115-25-3

Basic information

• Product Name: 3,9-di-2-furyl-2,4,8,10-tetraoxaspiro[5.5]undecane
• Synonyms: 3,9-di-2-furyl-2,4,8,10-tetraoxaspiro[5.5]undecane;3,9-Bis(2-furyl)-2,4,8,10-tetraoxaspiro[5.5]undecane;3,9-Di(2-furanyl)-2,4,8,10-tetraoxaspiro[5.5]undecane;2,4,8,10-Tetraoxaspiro(5.5)undecane, 3,9-di-2-furanyl-;Einecs 225-847-5
• CAS NO: 5115-25-3
• Molecular Formula: C₁₅H₁₆O₆
• Molecular Weight: 292.28394
• EINECS: 225-847-5
• Mol File: 5115-25-3.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 436.3°C at 760 mmHg
• Flash Point: 232°C
• Appearance: /
• Density: 1.33g/cm³
• Vapor Pressure: 2.08E-07mmHg at 25°C
• Refractive Index: 1.57
• CAS DataBase Reference: 3,9-di-2-furyl-2,4,8,10-tetraoxaspiro[5.5]undecane(CAS DataBase Reference)
• NIST Chemistry Reference: 3,9-di-2-furyl-2,4,8,10-tetraoxaspiro[5.5]undecane(5115-25-3)
• EPA Substance Registry System: 3,9-di-2-furyl-2,4,8,10-tetraoxaspiro[5.5]undecane(5115-25-3)

Safety Data

• Hazardous Substances Data: 5115-25-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H16O6/c1-3-11(16-5-1)13-18-7-15(8-19-13)9-20-14(21-10-15)12-4-2-6-17-12/h1-6,13-14H,7-10H2

Upstream product

• 98-01-1 furfural 
• 115-77-5 Pentaerythritol 
• 82515-50-2 2,2-bis(hydroxymethyl)propane-1,3-diol 

Relevant articles and documents

Acetalization of carbonyl compounds as pentaerythritol diacetals and diketals in the presence of cellulose sulfuric acid as an efficient, biodegradable and reusable catalyst

This paper reports a practical and green method for the acetalization of carbonyl compounds as pentaerythritol diacetals and diketals derivatives using cellulose sulfuric acid as a biodegradable and reusable solid acid catalyst under thermal solvent-free conditions.

SO3H-functionalized ionic liquids as efficient and recyclable catalysts for the synthesis of pentaerythritol diacetals and diketals

The efficient, simple and environmentally friendly synthesis of pentaerythritol diacetals and diketals using SO3H-functionalized ionic liquids (ILs) as catalysts was reported. The ILs showed high catalytic activities and reusabilities with good to excellent yields of the desired products. H0 (Hammett function) values and the minimum-energy geometries of SO3H-functionalized ILs were determined and the results revealed that the acidities and catalytic activities of ILs in acetalization were related to their structures. The IL [PSPy][OTf] with the shortest H-O bond distance had the strongest acidity and the highest catalytic activity in the synthesis of pentaerythritol diacetals and diketals.

Synthesis of diacetals from aldehydes and ketones with pentaerythritol catalysed by the ZrO2/S2O82- solid superacid

A manipulatively simple and rapid procedure for the synthesis of diacetals from 2,2-bis(hydroxymethyl)-1, 3-propanediol with aldehydes and ketones in refluxing benzene or toluene using the ZRO2/S2O 82- solid superacid as catalyst in 80-98% yields has been described.