5117-13-5

Basic information

• Product Name: N-METHACRYLOYLMORPHOLINE
• Synonyms: N-METHACRYLOYLMORPHOLINE;4-(2-methyl-1-oxoallyl)morpholine;1-Morpholino-2-methyl-2-propene-1-one;4-(2-Methyl-1-oxo-2-propenyl)morpholine;4-Methacryloylmorpholine;2-methyl-1-morpholin-4-yl-prop-2-en-1-one;2-methyl-1-morpholin-4-ylprop-2-en-1-one;2-methyl-1-morpholino-prop-2-en-1-one
• CAS NO: 5117-13-5
• Molecular Formula: C₈H₁₃NO₂
• Molecular Weight: 155.19
• EINECS: 225-853-8
• Mol File: 5117-13-5.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 311°C at 760 mmHg
• Flash Point: 141.9°C
• Appearance: /
• Density: 1.05g/cm³
• Vapor Pressure: 0.000578mmHg at 25°C
• Refractive Index: 1.475
• Storage Temp.: 2-8°C
• CAS DataBase Reference: N-METHACRYLOYLMORPHOLINE(CAS DataBase Reference)
• NIST Chemistry Reference: N-METHACRYLOYLMORPHOLINE(5117-13-5)
• EPA Substance Registry System: N-METHACRYLOYLMORPHOLINE(5117-13-5)

Safety Data

• Hazardous Substances Data: 5117-13-5(Hazardous Substances Data)

Usage

General Description

N-Methacryloylmorpholine is a chemical compound that is derived from methacrylic acid and morpholine. It is commonly used in various industrial applications, particularly in the production of polymer materials such as resins, adhesives, and coatings. N-Methacryloylmorpholine is known for its ability to improve adhesion, flexibility, and water resistance in these materials. It is also utilized as a reactive diluent in the formulation of UV-curable coatings and in the synthesis of biocompatible polymers for medical and cosmetic purposes. Additionally, this chemical is valued for its low volatility and low toxicity, making it a preferred choice for various industrial processes.

InChI:InChI=1/C8H13NO2/c1-7(2)8(10)9-3-5-11-6-4-9/h1,3-6H2,2H3

Upstream product

• 13887-51-9 2-bromo-2-methyl-1-morpholinopropan-1-one 
• 760-93-0 methacryloyl anhydride 
• 3773-84-0 β-morpholinyl-N,N-morpholinylpropionic acid amide 
• 110-91-8 morpholine 
• 920-46-7 Methacryloyl chloride 
• 30668-14-5 1-morpholinopropane-1-one 
• 50-00-0 formaldehyd 

Relevant articles and documents

Generation of stereochemically defined tetrasubstituted enolborinates by 1,4-hydroboration of α,β-unsaturated morpholine carboxamides with (diisopinocampheyl)borane

On all fours: The title reaction with (Ipc)2BH provides tetrasubstituted enolborinates which undergo aldol reactions with aldehydes to form products with all-carbon quaternary centers with exceptional diastereo- and enantioselectivity. A change to the substitution pattern of the starting amide leads to either diastereomer of the α-methyl-α-ethyl-β-hydroxy carboxamide (1 or 2). Copyright

Effect of Transition Metals on Chemodivergent Cross-Coupling of Acrylamides with Vinyl Acetate via C-H Activation

A novel chemodivergent cross-coupling of acrylamides and vinyl acetates has been realized via metal-catalyzed vinylic C-H activation. The selective olefinic C-H vinylation and alkenylation reaction was examined with a variety of differently functionalized acrylamides. The reaction efficiently generates a range of highly synthetically valuable butadienes with good functional group tolerance in good to moderate yields. A possible catalytic reaction mechanism involving the chelation-assisted olefinic C-H activation via an acetate-assisted deprotonation pathway is proposed.

Preparation method of single-functionality or multi-functionality acrylamide type compounds

The present invention relates to the field of new material fine chemicals, particularly to a new mild, efficient and economical preparation process technology of a class of single-functionality or multi-functionality acrylamide type compounds, wherein the materials are important alkene-containing unsaturated compounds, and are increasingly used in radiation polymerization curing materials or medical application materials and other fields.