51186-88-0

Basic information

• Product Name: m-phenoxybenzyl (1R-cis)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
• Synonyms: m-phenoxybenzyl (1R-cis)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate;Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, (3-phenoxyphenyl)methyl ester, (1R,3S)-;d-cis-Phenothrin
• CAS NO: 51186-88-0
• Molecular Formula: C₂₃H₂₆O₃
• Molecular Weight: 350.45074
• EINECS: 257-040-9
• Mol File: 51186-88-0.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 437°C at 760 mmHg
• Flash Point: 186.6°C
• Appearance: /
• Density: 1.12g/cm³
• Vapor Pressure: 7.77E-08mmHg at 25°C
• Refractive Index: 1.588
• CAS DataBase Reference: m-phenoxybenzyl (1R-cis)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: m-phenoxybenzyl (1R-cis)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate(51186-88-0)
• EPA Substance Registry System: m-phenoxybenzyl (1R-cis)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate(51186-88-0)

Safety Data

• Hazardous Substances Data: 51186-88-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C23H26O3/c1-16(2)13-20-21(23(20,3)4)22(24)25-15-17-9-8-12-19(14-17)26-18-10-6-5-7-11-18/h5-14,20-21H,15H2,1-4H3/t20-,21-/m1/s1

Upstream product

• 79-37-8 oxalyl dichloride 
• 13826-35-2 3-Phenoxybenzyl alcohol 
• 13499-05-3 hafnium tetrachloride 
• 10453-89-1 chrysanthemumic acid 
• 10026-11-6 zirconium(IV) chloride 
• 884846-74-6 vinyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate 

Downstream Products

• 68086-49-7 (1R,3S)-3-((Z)-2-Chloro-3,3,3-trifluoro-propenyl)-2,2-dimethyl-cyclopropanecarboxylic acid 3-phenoxy-benzyl ester 
• 107686-47-5 (3-phenoxyphenyl)methyl (1RS,3SR)-3-(2,2-dichloro-3,3,3-trifluoro-1-hydroxypropyl)-2,2-dimethylcyclopropanecarboxylate 
• 107686-50-0 (3-phenoxyphenyl)methyl (1RS,3SR)-3-(1-acetoxy-2,2-dichloro-3,3,3-trifluoropropyl)-2,2-dimethylcyclopropanecarboxylate 

Relevant articles and documents

Method for producing cyclopropanecarboxylates

There is disclosed a method for producing cyclopropanecarboxylates of the formula (3): by transesterification in the presence of a lanthanoid metal alkoxide

Asymmetric copper complex and cyclopropanation reaction using the same

There are disclosed asymmetric copper complex comprising, as components, (a) an optically active bisoxazoline compound of formula (1): wherein R1 and R2 are different and each represent a hydrogen atom, an alkyl group, a cycloalkyl group, or a phenyl or aralkyl group which may be substituted, R3 and R4 each represent a hydrogen atom, an alkyl group, a cycloalkyl group, or a phenyl or aralkyl group which may be substituted, or R3 and R4 may be bonded to each other to form a C3-5 cyclic alkylene group, R5 represents a hydrogen atom or a C1-6 alkyl group, or the two R5 groups may be bonded to each other to represent a C3-5 cyclic alkylene group, (b) a monovalent or divalent copper compound, and (c) a strong acid or a Lewis acid or a mixture thereof, and a process for producing an optically active cyclopropanecarboxylate using the same.

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