51226-29-0Relevant articles and documents
Identification of a degradation intermediate of the momilactone A rice phytoalexin by the rice blast fungus
Imai, Takuya,Ohashi, Yuko,Mitsuhara, Ichiro,Seo, Shigemi,Toshima, Hiroaki,Hasegawa, Morifumi
, p. 414 - 416 (2012)
We have already shown that major rice diterpene phytoalexin, momilactone A, was detoxified by Magnaporthe oryzae. We report here the identification by NMR, MS, and chemical synthesis of 3,6-dioxo-19-nor-9α-pimara-7,15-diene (1) as the degradation intermediate. Compound 1 exhibited similar antifungal activity to that of momilactone A, indicating 1 to be a precursor of possible detoxified compounds.