51268-88-3 Usage
Description
(+)-CIS-1(R),2(S)-1,2-DIHYDROXY-1,2-DIHYDRONAPHTHALENE, also known as (-)-(1R,2S)-1,2-Dihydro-1,2-naphthalenediol, is a derivative of Naphthalene, a polycyclic aromatic hydrocarbon. It is characterized by its unique chemical structure and properties, making it a versatile compound with potential applications in various industries.
Uses
Used in Chemical Synthesis:
(+)-CIS-1(R),2(S)-1,2-DIHYDROXY-1,2-DIHYDRONAPHTHALENE is used as a key intermediate in the synthesis of various organic compounds, particularly those with pharmaceutical and industrial applications. Its unique structure allows for the creation of novel molecules with potential benefits in these fields.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, (+)-CIS-1(R),2(S)-1,2-DIHYDROXY-1,2-DIHYDRONAPHTHALENE is used as a building block for the development of new drugs. Its chemical properties make it a valuable component in the design and synthesis of innovative therapeutic agents.
Used in Environmental Applications:
Due to its origin from Naphthalene, a compound found in tobacco smoke and urban air, (+)-CIS-1(R),2(S)-1,2-DIHYDROXY-1,2-DIHYDRONAPHTHALENE can be utilized in environmental applications, such as the development of methods to detect and mitigate the presence of harmful pollutants in the atmosphere.
Used in Material Science:
The unique properties of (+)-CIS-1(R),2(S)-1,2-DIHYDROXY-1,2-DIHYDRONAPHTHALENE also make it a candidate for use in the development of new materials with specific characteristics, such as improved strength, durability, or chemical resistance.
Check Digit Verification of cas no
The CAS Registry Mumber 51268-88-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,1,2,6 and 8 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 51268-88:
(7*5)+(6*1)+(5*2)+(4*6)+(3*8)+(2*8)+(1*8)=123
123 % 10 = 3
So 51268-88-3 is a valid CAS Registry Number.
InChI:InChI=1/C10H10O2/c11-9-6-5-7-3-1-2-4-8(7)10(9)12/h1-6,9-12H/t9-,10+/m0/s1
51268-88-3Relevant articles and documents
Rhodium(I)-catalyzed domino asymmetric ring opening/enantioselective isomerization of oxabicyclic alkenes with water
Tsui, Gavin C.,Lautens, Mark
supporting information; experimental part, p. 5400 - 5404 (2012/07/03)
Water-induced asymmetric ring opening: Enantio-enriched 2-hydroxy-1-tetralones are formed from oxabicyclic alkenes through a novel RhI-catalyzed domino reaction. The proposed mechanism involves water-induced asymmetric ring opening to generate chiral trans-1,2-diol intermediates and subsequent enantioselective isomerization (see scheme). Copyright
Bio-inspired arene cis-dihydroxylation by a non-haem iron catalyst modeling the action of naphthalene dioxygenase
Feng, Yan,Ke, Chun-Yen,Xue, Genqiang,Que Jr., Lawrence
body text, p. 50 - 52 (2009/03/11)
Reported in this paper is the first example of a biomimetic iron complex, ([FeII(TPA)(NCMe)2]2+ (TPA = tris(2-pyridylmethyl)amine), that catalyses the cis-dihydroxylation of an aromatic double bond, mimicking the action of
Bioconversion of substituted naphthalenes to the corresponding 1,2-dihydro derivatives by Escherichia coli recombinant strains
Di Gennaro, Patrizia,Bestetti, Giuseppina,Galli, Enrica,Orsini, Fulvia,Pelizzoni, Francesca,Sello, Guido
, p. 6267 - 6270 (2007/10/03)
1,2-dihydroxynaphthalenes are produced by bioconversion of the corresponding hydrocarbons using Escherichia coli recombinant strains containing the naphthalene dioxygenase and dehydrogenase genes cloned from pseudomonas fluorescens N3. Conversions are lead by a two step procedure without isolation of the dihydrodiol intermediate. Conversion rates depend on the position and nature of the naphthalene substituent.
