51384-73-7Relevant articles and documents
Lewis Acid Catalyzed Ring-Opening Reaction of Cyclobutanones towards Conjugated Enones
Gao, Jiqiang,Guo, Ziteng,Li, Zhongjuan,Liu, Chunhui,Liu, Yu,Qiu, Tingtian,Zhang, Min,Zhao, Jinbo
, p. 6111 - 6114 (2021/12/16)
An unprecedented Fe-catalyzed ring-opening reaction of simple cyclobutanones is developed, which provides access to conjugated enones with good functional group tolerance in high yields under mild conditions. The product derivatization and gram-scale expe
Rearrangement Reactions Leading to Optically Active α,α-Disubstituted Primary Allylamines
Hennum, Martin,Odden, Hege Hortemo,Gundersen, Lise-Lotte
, p. 846 - 860 (2017/02/15)
Synthetic routes to α,α-disubstituted allylamines have been examined. Racemic compounds were conveniently prepared by thermal Overman rearrangements of primary allylic alcohols with trisubstituted double bonds, but rearrangement of these substrates using
Catalytic stereospecific allyl-allyl cross-coupling of internal allyl electrophiles with allylB(pin)
Le, Hai,Batten, Amanda,Morken, James P.
supporting information, p. 2096 - 2099 (2014/05/06)
Application of internal electrophiles in catalytic stereospecific allyl-allyl cross-coupling enable the rapid construction of multisubstituted 1,5-dienes, including those with all carbon quaternary centers. Compounds with minimal steric differentiation ca
