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516-03-0

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516-03-0 Usage

Description

Ferrous oxalate, also known as iron (II) oxalate, is a chemical compound with the chemical formula FeC2O4. It is more commonly found as the dihydrate, FeC2O4·2H2O, and consists of one iron (II) ion (Fe2+) and one oxalate ion (C2O42-). Ferrous oxalate is an odorless, pale-yellow, crystalline powder that is soluble in acids but insoluble in water. It has a crystal structure made up of chains of oxalate-bridged iron atoms, capped by water molecules. Upon heating, it dehydrates and decomposes into carbon dioxide, carbon monoxide, iron oxides, and pyrophoric black iron.

Uses

Used in Photography Industry:
Ferrous oxalate is used as a photographic developer for its ability to develop images on photographic film and paper. It is known for its effectiveness in producing high-quality images with good contrast and detail.
Used in Glass Industry:
In the glass industry, ferrous oxalate is used as a glass tint and decorative glass colorant. It imparts a yellow color to the glass, making it suitable for creating decorative glass items and colored glass products.
Used in Plastics Industry:
Ferrous oxalate is utilized as a pigment in the plastics industry. Its yellow coloration adds visual appeal to various plastic products, enhancing their aesthetic value and making them more attractive to consumers.
Used in Paints and Lacquers Industry:
Ferrous oxalate is also used as a pigment in the production of paints and lacquers. Its color-enhancing properties contribute to the creation of vibrant and long-lasting coatings for various applications, including automotive, architectural, and industrial coatings.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Inorganic reducing agents, such as Ferrous oxalate, react with oxidizing agents to generate heat and products that may be flammable, combustible, or otherwise reactive.

Hazard

Toxic. Evolves carbon monoxide on heating.

Health Hazard

Inhalation of dust may cause irritation of nose and throat. Ingestion causes burning pain in throat and stomach; mucous membranes turn white; can also cause vomiting, weak pulse, collapse, and death. Dust irritates eyes and may irritate skin on prolonged contact.

Fire Hazard

Special Hazards of Combustion Products: Iron fume or iron oxide fume may form in fire.

Flammability and Explosibility

Notclassified

Check Digit Verification of cas no

The CAS Registry Mumber 516-03-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,1 and 6 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 516-03:
(5*5)+(4*1)+(3*6)+(2*0)+(1*3)=50
50 % 10 = 0
So 516-03-0 is a valid CAS Registry Number.
InChI:InChI=1/C2H2O4.Fe/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2

516-03-0 Well-known Company Product Price

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  • Alfa Aesar

  • (39261)  Iron(II) oxalate hydrate, 96%   

  • 516-03-0

  • 500g

  • 443.0CNY

  • Detail
  • Alfa Aesar

  • (39261)  Iron(II) oxalate hydrate, 96%   

  • 516-03-0

  • 2kg

  • 1395.0CNY

  • Detail

516-03-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name Iron(II) oxalate hydrate

1.2 Other means of identification

Product number -
Other names Ferrous oxalate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:516-03-0 SDS

516-03-0Synthetic route

tin(II) chloride dihdyrate
10025-69-1

tin(II) chloride dihdyrate

iron(III) oxalate pentahydrate

iron(III) oxalate pentahydrate

A

tin(IV) chloride tetrahydrate

tin(IV) chloride tetrahydrate

B

Sn(2+)*C2O4(2-)*3H2O=SnC2O4*3H2O

Sn(2+)*C2O4(2-)*3H2O=SnC2O4*3H2O

FeC2O4, α
516-03-0

FeC2O4, α

Conditions
ConditionsYield
In neat (no solvent, solid phase) Solid state reaction in hydrogen or helium atmosphere.; Gas chromatography, Moessbauer spectroscopy.;
iron(III) oxalate pentahydrate

iron(III) oxalate pentahydrate

FeC2O4, α
516-03-0

FeC2O4, α

B

carbon dioxide
124-38-9

carbon dioxide

C

water
7732-18-5

water

Conditions
ConditionsYield
In neat (no solvent, solid phase) Solid state reaction in hydrogen or helium atmosphere.; Gas chromatography, Moessbauer spectroscopy.;

516-03-0Downstream Products

516-03-0Relevant articles and documents

Studies on solid state redox reaction of iron(III) oxalate by gas chromatography

Jinhua, Yuan,Xinquan, Xin,Anbang, Dai,Yuchang, Chang

, p. 51 - 60 (2008/10/08)

The solid state redox reaction of iron (III) oxalate with sodium nitrate and tin(II) chloride was investigated in hydrogen atmosphere and helium atmosphere by use of a non-isothermal technique. The evolved gases (EG) formed during the reaction were directly detected by gas chromatography, and the solid products were also identified by XRD, Moessbauer spectra and IR. The results show that the solid state redox reaction can go to completion because electron transfer is much easier than mass diffusion along the boundaries of the reactant. The releasing of crystal and coordination water during the redox reaction also facilitates completion of the reaction. The mechanism of the solid state reaction is also discussed.

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