51801-03-7Relevant articles and documents
Formation of symmetrical alkenes by homocoupling of metallated sulfones under nickel catalysis
Gai, Yonghua,Julia, Marc,Jean-Noe,Verpeaux
, p. 805 - 816 (2007/10/03)
Summary -Allylic sulfones undergo a coupling reaction with organometallic compounds (Mg or Li) not only with copper catalysts but also with iron or nickel salts. With 7,7-disubstituted allylic sulfones and also saturated aliphatic sulfones, however, another reaction was observed whereby two molecules of the starting sulfone are coupled to give symmetrical alkenes. The scope of this reaction was investigated. Elsevier.
ORGANIC SULFUR COMPOUNDS CONTAINING HETEROCYCLES. II: METHYL 2-PYRIDYL SULFOXIDE AS PHASE TRANSFER CATALYST.
Furukawa, Naomichi,Kishimoto, Keiko,Ogawa, Satoshi,Kawai, Tsutomu,Fujihara, Hisashi,Oae, Shigeru
, p. 4409 - 4412 (2007/10/02)
Methyl 2-pyridyl sulfoxide was found to be an excellent phase transfer catalyst which promotes simple SN2 type displacement reactions of alkyl halides with some nucleophiles.