51830-12-7Relevant articles and documents
Chloroperoxidase-catalyzed oxidation of conjugated dienoic esters
Bougioukou, Despina J,Smonou, Ioulia
, p. 339 - 342 (2007/10/03)
The chloroperoxidase (CPO)-catalyzed oxidations of dienes conjugated to an ester group were studied using tert-butyl hydroperoxide as the terminal oxidant.
Ruthenium-catalysed reductive cleavage of allylic esters with formic acid and triethylamine. Application to short-step synthesis of α-hydroxy acids
Maruyama, Yooichiroh,Sezaki, Takao,Tekawa, Masafumi,Sakamoto, Toshiaki,Shimizu, Isao,Yamamoto, Akio
, p. 257 - 264 (2007/10/02)
Ruthenium-catalysed reductive cleavage reactions of allylic carboxylates and carbonates with formic acid and triethylamine to give olefins were explored.As an application of the ruthenium-catalysed processes, a new synthetic route to α-hydroxy acids has been discovered.The reductive cleavage of allylic esters is considered to proceed through ?-allylruthenium intermediates. Key words: Ruthenium; Catalysis; Reductive cleavage; Allyl; Formic acid
Cobalt(II) complex catalysed epoxidation with molecular oxygen
Iqbal,Bhatia,Madhava Reddy
, p. 2285 - 2292 (2007/10/02)
Cobalt(II) complexes 1 or 2, catalyses the epoxidation of alkenes in the presence of molecular oxygen and 2-methylpropanal in high yields.