52056-71-0Relevant articles and documents
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Mikolajczyk,M.,Drabowicz,J.
, p. 124 - 126 (1974)
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THIO- AND OXO-ACIDS OF TRICOORDINATED SULFUR: SYNTHETIC AND STEREOCHEMICAL ASPECTS
Drabowicz, Jozef,Lyzwa, Piotr,Bujnicki, Bogdan,Mikolajczyk, Marian
, p. 293 - 312 (2007/10/02)
This account describes the first synthesis, characterization and reactivity of the relatively stable thiosulfinic acid salts.New approaches for the preparation of optically active sulfinic acid salts and sulfones, which are chiral due to 16O, 18O isotopic substitution, as well as measurement of their chirooptical properties are also presented.Key words: thiosulfinic acid salts, chiral 16O, 18O-sulfinic acids salts, sulfinyl chlorides, optically active sulfoxides, optically active 16O, 18O-sulfones, optical activity, circular dichroism.