5208-54-8

Basic information

• Product Name: (+/-)-(1R,3S)-m-menthan-8-ol
• CAS NO: 5208-54-8
• Molecular Weight: 156.268
• Mol File: 5208-54-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-(1R,3S)-m-menthan-8-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(1R,3S)-m-menthan-8-ol(5208-54-8)
• EPA Substance Registry System: (+/-)-(1R,3S)-m-menthan-8-ol(5208-54-8)

Safety Data

• Hazardous Substances Data: 5208-54-8(Hazardous Substances Data)

Upstream product

• 88211-23-8 (+)-(1S,5R)-3-oxabicyclo<3.3.1>nonan-2-one 
• 88211-29-4 cis-1,3-bis((benzyloxy)methyl)cyclohexane 
• 88211-20-5 (+/-)-cis-1-bromo-3,5-bis(hydroxymethyl)cyclohexene 
• 917-54-4 methyllithium 
• 7133-30-4 ethyl (1S,3R)-3-methylcyclohexanecarboxylate 
• 5208-31-1 (5S)-(-)-5β-(1-Hydroxy-1-methylethyl)-1-methyl-1,3-cyclohexadien 
• 88211-27-2 (+/-)-cis-1-acetoxy-3,5-bis((benzyloxy)methyl)cyclohexene 
• 88211-28-3 (7R,9S)-7,9-Bis-benzyloxymethyl-1,4-dithia-spiro[4.5]decane 
• 88211-21-6 cis-3,5-bis((benzyloxy)methyl)cyclohexanone 
• 88211-26-1 (+/-)-cis-1-bromo-3,5-bis((benzyloxy)methyl)cyclohexene 
• 5059-76-7 ((1R,3S)-cyclohexane-1,3-diyl)dimethanol 

Downstream Products

• 13837-66-6 (1S,3R)-(+)-cis-m-Menthan 
• 5208-55-9 (+)(1S:3R)-cis-Δ⁸-m-Menthen 
• 5208-56-0 (+)(1S)-Δ³⁽⁸⁾-m-Menthen 

Relevant articles and documents

3. 2. 1.

Preparative-scale horse liver alcohol dehydrogenase catalyzed oxidations of meso-1,3-bis(hydroxymethyl)cyclopentyl and -cyclohexyl substrates proceed stereospecifically to give 42-81% yields of the corresponding chiral bridged-bicyclic gamma -lactones of 100% ee. For each diol, oxidation of the hydroxymethyl group attached to the S center occurs exclusively. The stereospecificities observed are as predicted by the active-site model of the enzyme.