521065-36-1Relevant articles and documents
Synthetic method of oxalate lithium phosphate salt compound
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Paragraph 0037-0050; 0061-0062, (2020/11/26)
The invention discloses a synthetic method of an oxalate lithium phosphate salt compound. The synthetic method has the advantages of low reaction temperature and high product yield, and comprises thefollowing steps: mixing ammonium hexafluorophosphate or amine salt, silicon-based oxalate and lithium hydride in a non-aqueous solvent, and conducting reacting to obtain the oxalate lithium phosphatesalt compound. No chloride ions are introduced in the synthesis process, purity can reach 99%, and the produced compound can be directly used as an electrolyte additive without further treatment.
NONAQUEOUS ELECTROLYTE COMPOSITIONS COMPRISING SILYL OXALATES
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Paragraph 0277-0283, (2019/08/20)
Disclosed herein are electrolyte compositions comprising a fluorinated solvent, at least one silyl oxalate represented by the formulas RR′Si(C2O4), wherein R and R′ are each the same or different from each other and independently selected from C1-C8 alkyl, C2-C8 alkenyl, C2-C8 alkynyl, or C6-C10 aryl radical, optionally comprising at least one substituent selected from halogen, hydroxyl, alkoxy, carbonyl, and carboxyl groups; and LiPF6. Also disclosed herein are electrolyte compositions comprising a fluorinated solvent and a lithium oxalato phosphate salt represented by the formula LiPF(6-2q)(C2O4)q, wherein q is 1, 2 or 3; wherein the oxalato phosphate salt comprises at least a portion that is derived from at least one silyl oxalate as defined herein. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.