52132-66-8

Basic information

• Product Name: Benzene, [[(methylthio)methoxy]methyl]-
• CAS NO: 52132-66-8
• Molecular Formula: C9H12OS
• Molecular Weight: 168.26
• Mol File: 52132-66-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, [[(methylthio)methoxy]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[(methylthio)methoxy]methyl]-(52132-66-8)
• EPA Substance Registry System: Benzene, [[(methylthio)methoxy]methyl]-(52132-66-8)

Safety Data

• Hazardous Substances Data: 52132-66-8(Hazardous Substances Data)

Upstream product

• 67-68-5 dimethyl sulfoxide 
• 100-51-6 benzyl alcohol 

Downstream Products

• 3587-60-8 Benzyloxymethyl chloride 
• 103594-88-3 2-(benzyloxy)methoxy-5-chloropyrimidine 
• 88045-77-6 1-(benzyloxy)methyl-5-chloro-2(1H)-pyrimidinone 

Relevant articles and documents

Burgess Reagent Facilitated Alcohol Oxidations in DMSO

The Burgess reagent ([methoxycarbonylsulfamoyl]triethylammonium hydroxide) has historically found utility as a dehydrating agent. Herein we show that, in the presence of dimethyl sulfoxide, the Burgess reagent efficiently and rapidly facilitates the oxidation of a broad range of primary and secondary alcohols to their corresponding aldehydes and ketones in excellent yields and under mild conditions, and can be combined with other transformations (e.g., Wittig olefinations). A mechanism similar to those described for the Pfitzner-Moffatt and Swern oxidations is proposed.