52376-16-6 Usage
Description
1,4-Diacetoxy-2-bromobenzene, also known as 97, is an organic compound derived from 1,4-benzoquinone through a reaction with zinc bromide in the presence of acetic anhydride. It is characterized by its bromine atom and two acetoxy groups attached to the benzene ring, which contribute to its chemical properties and potential applications in various industries.
Uses
1. Used in Chemical Synthesis:
1,4-Diacetoxy-2-bromobenzene 97 is used as a key intermediate in the synthesis of various organic compounds, such as bromohydroquinone and (Sp,S)-1-(2,5-diacetoxyphenyl)-2-(p-tolylsulfinyl)ferrocene. Its unique structure allows for further chemical reactions and modifications, making it a valuable building block in the development of new molecules with specific properties and applications.
2. Used in Pharmaceutical Industry:
In the pharmaceutical industry, 1,4-Diacetoxy-2-bromobenzene 97 may be utilized as a starting material for the development of new drugs or drug candidates. Its chemical structure can be further modified to create compounds with potential therapeutic effects, targeting various diseases and medical conditions.
3. Used in Material Science:
1,4-Diacetoxy-2-bromobenzene 97 can also be employed in the field of material science, where its unique chemical properties may be harnessed to develop new materials with specific characteristics. These materials could have applications in various industries, such as electronics, automotive, or aerospace.
4. Used in Research and Development:
As a versatile organic compound, 1,4-Diacetoxy-2-bromobenzene 97 is also used in research and development laboratories. Scientists and researchers can explore its chemical properties and potential applications, leading to the discovery of new compounds and technologies that can benefit various industries.
Check Digit Verification of cas no
The CAS Registry Mumber 52376-16-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,2,3,7 and 6 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 52376-16:
(7*5)+(6*2)+(5*3)+(4*7)+(3*6)+(2*1)+(1*6)=116
116 % 10 = 6
So 52376-16-6 is a valid CAS Registry Number.
InChI:InChI=1/C10H9BrO4/c1-6(12)14-8-3-4-10(9(11)5-8)15-7(2)13/h3-5H,1-2H3
52376-16-6Relevant articles and documents
Total synthesis of (±)-ganocins B and C
Liu, Yao,Zhou, Chu-Jun,Li, Qingjiang,Wang, Honggen
, p. 10362 - 10365 (2016)
The first total synthesis of structurally unique polycyclic phenolic meroterpenoids, ganocins B and C is reported. The synthesis features gold-catalyzed intramolecular cascade cyclization to construct the C/D ring bearing an angular methyl group, diastereoselective Michael addition, and acid-mediated one-pot Robinson cyclization/deprotection/isomerization.
Efficient synthesis of 5-nitro-benzo[b]furans via 2-bromo-4-nitro-phenyl acetates
Bochicchio, Antonella,Chiummiento, Lucia,Funicello, Maria,Lopardo, Maria Teresa,Lupattelli, Paolo
experimental part, p. 2824 - 2827 (2010/07/04)
Acetylation/Sonogashira cross-coupling reaction/cyclization has been carried out in one-pot using a Na2PdCl4/2-(di-tert-butylphosphino)-N-phenylindole/CuI system in TMEDA to give 5-nitro-2-substituted benzo[b]furans in excellent yields. We also describe the extension of this method to 4-EWG-2-bromo-phenols obtaining 2,5-disubstituted-benzo[b]furans in good yields.
Formal total synthesis of shikonin via D?tz benzannulation
Pulley, Shon R.,Czakó, Barbara
, p. 5511 - 5514 (2007/10/03)
The D?tz benzannulation reaction provides mild conditions for the construction of highly functionalized aromatic compounds. We have utilized this method for the formal total synthesis of shikonin. The key step in our approach is the application of the D?tz benzannulation reaction between Fischer a chromium carbene complex and an optically active alkyne for the construction of the aromatic skeleton. This is followed by protecting group manipulation and formation of the epoxide moiety using the Sharpless procedure.
