52418-74-3Relevant articles and documents
Nickel-Catalyzed Conjugate Addition of Alkynyl Groups to α,β-Unsaturated Ketones
Schwartz, Jeffrey,Carr, Denise B.,Hansen, Robert T.,Dayrit, Fabian M.
, p. 3053 - 3061 (2007/10/02)
The complex formed by reaction of Ni(acac)2 and DiBAH (1:1) catalyzes conjugate addition of dialkylaluminium acetylides to α,β enones; on hydrolysis, 3-alkynyl ketones are produced in high yield.Through this procedure conjugate addition of alkynyl groups
Novel 2-substituted-3,4-epoxycyclopentan-1-ones, 2-substituted-3,4-epoxycyclopentan-1-ols, and various 2-substituted-cyclopentenones
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, (2008/06/13)
This disclosure describes novel 4-oxy-2-substituted-cyclopent-2-en-1-ones useful as intermediates for the preparation of homo and nor prostaglandins of the E2, E3 and F series.
Hydro substituted prostanoic acids and esters
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, (2008/06/13)
This disclosure describes certain 11-hydroxy and 11-deoxy-9-keto (or hydroxy)prostanoic acid derivatives useful as bronchodilators, anti-ulcer agents, or as intermediates.