52497-56-0

Basic information

• Product Name: (E)-2-methyl-4-phenyl-but-2-en-1-ol
• Synonyms: (E)-2-methyl-4-phenyl-but-2-en-1-ol
• CAS NO: 52497-56-0
• Molecular Weight: 162.232
• Mol File: 52497-56-0.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: (E)-2-methyl-4-phenyl-but-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-methyl-4-phenyl-but-2-en-1-ol(52497-56-0)
• EPA Substance Registry System: (E)-2-methyl-4-phenyl-but-2-en-1-ol(52497-56-0)

Safety Data

• Hazardous Substances Data: 52497-56-0(Hazardous Substances Data)

Upstream product

• 75593-21-4 2-methyl-3-phenylsulphinyl-4-phenylbut-1-ene 
• 36219-40-6 1-bromo-2-hydroxy-2-methyl-3-butene 
• 591-51-5 phenyllithium 
• 443288-09-3 (Z)-2-methyl-3-trimethylsilyl-4-phenyl-2-buten-1-ol 
• 443287-93-2 (Z)-methyl 2-methyl-3-trimethylsilyl-4-phenyl-2-butenoate 
• 665004-92-2 (Z)-2-methyl-3-trimethylsilyl-4-phenyl-2-butenoic acid 
• 96548-13-9 4-methyl-4-vinyl-1,3-dioxolan-2-one 
• 98-80-6 phenylboronic acid 
• 14182-67-3 2-methyl-4-phenyl-but-2-enoic acid ethyl ester 
• 934-56-5 trimethyl(phenyl)stannane 
• 1838-94-4 isoprene epoxide 
• 98713-50-9 2-methyl-4-phenyl-3-phenylthiobut-1-ene 
• 56583-94-9 (phenylacetyl)trimethylsilane 
• 917-54-4 methyllithium 

Downstream Products

• 153831-77-7 ((2R,3R)-3-benzyl-2-methyloxiran-2-yl)methanol 
• 55177-36-1 (2E)-2-methyl-4-phenylbut-2-enal 

Relevant articles and documents

Cross-coupling of vinylethylene carbonates with arylboronic acids catalyzed by in situ generated palladium nanoparticles in water

A practical and greener method of the cross-coupling of vinylethylene carbonates (VECs) with arylboronic acids has been described. The coupling reaction was catalyzed by in situ generated palladium nanoparticles (PdNPs) without any ligands and additional stabilizers in water under ambient conditions to provide useful 4-hydroxylprenylarenes and their derivatives in good to high yields.

Convergent synthesis of (2R,3R,8R,9R)-N-Boc-ADDA

(Figure Presented) The convergent synthesis of N-Boc-(2R,3R,8R,9R,4E,6E)-3- amino-9-methoxy-2,6,8-trimethyl-10-phenyldecadenoic acid (enantio-N-Boc-ADDA) is reported. Our flexible approach takes advantage of highly efficient non-aldol aldol and cross-metathesis methodologies.

Stereospecific synthesis of aldols

Methods are provided for preparing all four diastereomers of 2-alkyl-3-hydroxyalkanals, 2-alkyl-3-silyloxyalkanals, and the like, with high enantiocontrol, using non-aldol chemistry. The synthetic methods also provide novel, stereospecific routes to polyp