52708-37-9

Basic information

• Product Name: 4-(9H-Carbazol-9-yl)aniline
• Synonyms: N-(4-Aminophenyl)carbazole;9-(4-Aminophenyl)carbazole;9-(4-Aminophenyl)-9H-carbazole;9-(4-Aminobenzene)carbazole;4-Carbazol-9-ylaniline;4-(9H-Carbazol-9-yl)benzenamine;4-(9H-carbazol-9-yl)-
• CAS NO: 52708-37-9
• Molecular Formula: C₁₈H₁₄N₂
• Molecular Weight: 258.31716
• Mol File: 52708-37-9.mol
• Article Data: 49

Chemical Properties

• Melting Point: 96 °C
• Boiling Point: 475.0±37.0 °C(Predicted)
• Appearance: /
• Density: 1.19±0.1 g/cm3(Predicted)
• Storage Temp.: 2-8°C
• Solubility: soluble in Toluene
• PKA: 3.47±0.10(Predicted)
• CAS DataBase Reference: 4-(9H-Carbazol-9-yl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(9H-Carbazol-9-yl)aniline(52708-37-9)
• EPA Substance Registry System: 4-(9H-Carbazol-9-yl)aniline(52708-37-9)

Safety Data

• Hazardous Substances Data: 52708-37-9(Hazardous Substances Data)

Usage

Uses

4-(Carbazol-9-yl)aniline

Upstream product

• 16982-76-6 9-(4-nitrophenyl)-9H-carbazole 
• 57103-11-4 9-((4-acetamido)phenyl)carbazole 
• 636-98-6 p-nitrobenzene iodide 
• 86-74-8 9H-carbazole 
• 350-46-9 4-Fluoronitrobenzene 
• 98-95-3 nitrobenzene 
• 13029-09-9 2,2'-dibromobiphenyl 
• 106-50-3 1,4-phenylenediamine 
• 371-40-4 4-fluoroaniline 
• 586-78-7 para-nitrophenyl bromide 
• 1806-29-7 2,2'-dihydroxybiphenyl 
• 17763-95-0 2,2'-bis-<<(trifluoromethyl)sulfonyl>oxy>biphenyl 
• 540-37-4 p-aminoiodobenzene 
• 100-00-5 4-chlorobenzonitrile 

Downstream Products

• 53167-75-2 4-(9H-carbazol-9-yl)-N,N-dimethylaniline 
• 1228784-77-7 9-(4-isocyanophenyl)carbazole 
• 1228784-79-9 [Au(C₆F₅)(9-(4-isocyanophenyl)carbazole)] 

Relevant articles and documents

Method for synthesizing carbazole derivative

The invention aims to provide a method for synthesizing a carbazole derivative. The method is characterized in that palladium chloride is used as a catalyst, 2, 2' - dibromobiphenyl is used as an electrophilic reagent, primary amine is taken as a nucleophile, and the carbazole derivative is directly cross-coupled under the conditions of toluene as a solvent and an air atmosphere. The method has the advantages of high yield, high selectivity, simplicity and convenience in operation and the like.

Fluorescent carbazole-containing dyes: Synthesis and supramolecular assembly by self-complementary donor-acceptor π-stacking and dipolar interactions

Six carbazole-based dyes were synthesized by fluorescence turn on amino-ene click reactions. Two high quality single-crystals of new dyes were prepared, and their X-ray diffraction structure analyses reveal the formation of antiparallel stacking superstructures driven by self-complementary dipole-dipole and π-stacking interactions between carbazole donors and acceptors. The optical behaviors and donor-acceptor interactions of these dyes were investigated by ultraviolet–visible absorption, fluorescence emission spectroscopy, and electrochemical cyclic voltammetry. Blue fluorescence appears and increases as dye-based supramolecular polymer grows, as revealed by dynamic light scattering, fluorescence, 1H NMR and 2D NMR spectroscopy.

Protonation-induced dual fluorescence of a blue fluorescent material with twisted A-π-D-π-A configuration

In this work, we introduced a blue fluorescent material with twisted A-π-D-π-A configuration, namely CzPA-F-PD. This compound exhibits remarkable dual fluorescence properties triggered by trifluoroacetic acid (TFA), resulting in blue and red emission peak