527737-44-6

Basic information

• Product Name: Benzenesulfonamide, N-(2,2-diphenyl-4-pentenyl)-4-methyl-
• CAS NO: 527737-44-6
• Molecular Formula: C24H25NO2S
• Molecular Weight: 391.534
• Mol File: 527737-44-6.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-(2,2-diphenyl-4-pentenyl)-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-(2,2-diphenyl-4-pentenyl)-4-methyl-(527737-44-6)
• EPA Substance Registry System: Benzenesulfonamide, N-(2,2-diphenyl-4-pentenyl)-4-methyl-(527737-44-6)

Safety Data

• Hazardous Substances Data: 527737-44-6(Hazardous Substances Data)

Upstream product

• 1162740-22-8 2,2-diphenylpent-4-en-1-amine hydrochloride salt 
• 98-59-9 p-toluenesulfonyl chloride 
• 5558-71-4 2,2-diphenyl-pent-4-enenitrile 
• 86-29-3 Diphenylacetonitrile 
• 53001-06-2 2,2-diphenyl-4-pentenylamine 

Downstream Products

• 1245741-88-1 2-benzyl-4,4-diphenyl-1-tosylpyrrolidine 
• 1269218-92-9 3-methoxy-5,5-diphenyl-1-tosylpiperidine 
• 1269219-00-2 C₂₅H₂₇NO₃S 
• 1269218-93-0 3-acetoxy-5,5-diphenyl-1-tosylpiperidine 
• 1269219-01-3 C₂₆H₂₇NO₄S 
• 1356133-39-5 (R)-2-(3,3-diphenylallyl)-4,4-diphenyl-1-tosylpyrrolidine 
• 1207278-30-5 5,5-diphenyl-1-tosylpiperidin-3-ol 
• 1269218-99-6 (4,4-diphenyl-1-tosylpyrrolidin-2-yl)methanol 
• 1269219-04-6 N-(5,5-diphenyl-1-tosylpiperidin-3-yl)acetamide 
• 1196712-28-3 5-fluoro-3,3-diphenyl-1-tosylpiperidine 
• 1094359-32-6 1-[4,4-diphenyl-1-(toluene-4-sulfonyl)-pyrrolidin-2-ylmethoxy]-2,2,6,6-tetramethyl-piperidine 
• 958870-30-9 7-methyl-2,2-diphenyl-2,3,9,9a-tetrahydro-1H-4-thia-3a-aza-(S)-cyclopenta[b]naphthalene-4,4-dioxide 

Relevant articles and documents

Manganese-Catalyzed N-F Bond Activation for Hydroamination and Carboamination of Alkenes

A visible-light-promoted method for generating amidyl radicals from N-fluorosulfonamides via a manganese-catalyzed N-F bond activation strategy is reported. This protocol employs a simple manganese complex, Mn2(CO)10, as the precatalyst and a cheap silane, (MeO)3SiH, as both the hydrogen-atom donor and the F-atom acceptor, enabling intramolecular/intermolecular hydroaminations of alkenes, two-component carboamination of alkenes, and even three-component carboamination of alkenes. A wide range of valuable aliphatic sulfonamides can be readily prepared using these practical reactions.

Enantioselective Pd(II)-Catalyzed Intramolecular Oxidative 6- endo Aminoacetoxylation of Unactivated Alkenes

A novel asymmetric 6-endo aminoacetoxylation of unactivated alkenes by palladium catalysis, which yields chiral β-acetoxylated piperidines with excellent chemo-, regio- and enantioselectivities under very mild reaction conditions, has been established herein by employing a new designed pyridine-oxazoline (Pyox) ligand. Importantly, introducing a sterically bulky group into the C-6 position of Pyox is crucial to enhance the reactivity of the aminoacetoxylation of alkenes.

Copper-Promoted Intramolecular Aminotrifluoromethylation of Alkenes with Langlois Reagent as the Trifluoromethyl Source

A novel approach for copper-promoted intramolecular aminotrifluoromethylation of alkenes using inexpensive CF3SO2Na as the trifluoromethyl source is described. The feature of this method is the concurrent construction of a five-membered ring and a C-CF3 bond in the simple copper salt/TBHP system. A gram-scale reaction was tested with a slight decrease in the yield. This protocol provides an operationally simple, step-economical and synthetically useful access to a variety of trifluoromethyl indolines, pyrrolidines and lactams.